Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
[Illustration: Fig. 8. Diagram of the products obtained from coal and
some of their uses.]
The most important of the ten because he is the father of the family is
benzene, otherwise called benzol, but must not be confused with
"benzine" spelled with an _i_ which we used to burn and clean our
clothes with. "Benzine" is a kind of gasoline, but benzene _alias_
benzol has quite another constitution, although it looks and burns the
same. Now the search for the constitution of benzene is one of the most
exciting chapters in chemistry; also one of the most intricate chapters,
but, in spite of that, I believe I can make the main point of it clear
even to those who have never studied chemistry--provided they retain
their childish liking for puzzles. It is really much like putting
together the old six-block Chinese puzzle. The chemist can work better
if he has a picture of what he is working with. Now his unit is the
molecule, which is too small even to analyze with the microscope, no
matter how high powered. So he makes up a sort of diagram of the
molecule, and since he knows the number of atoms and that they are
somehow attached to one another, he represents each atom by the first
letter of its name and the points of attachment or bonds by straight
lines connecting the atoms of the different elements. Now it is one of
the rules of the game that all the bonds must be connected or hooked up
with atoms at both ends, that there shall be no free hands reaching out
into empty space. Carbon, for instance, has four bonds and hydrogen only
one. They unite, therefore, in the proportion of one atom of carbon to
four of hydrogen, or CH_{4}, which is methane or marsh gas and obviously
the simplest of the hydrocarbons. But we have more complex hydrocarbons
such as C_{6}H_{14}, known as hexane. Now if you try to draw the
diagrams or structural formulas of these two compounds you will easily
get
H H H H H H H
| | | | | | |
H-C-H H-C-C-C-C-C-C-H
| | | | | | |
H H H H H H H
methane hexane
Each carbon atom, you see, has its four hands outstretched and duly
grasped by one-handed hydrogen atoms or by neighboring carbon atoms in
the chain. We can have such chains as long as you please, thirty or more
in a chain; they are all contained in kerosene and paraffin.
So far the chemist found it east to construct diagrams that would
satisfy his sense of the fitness of things, but when he found that
benzene had the compostion C_{6}H_{6} he was puzzled. If you try to draw
the picture of C_{6}H_{6} you will get something like this:
| | | | | |
-C-C-C-C-C-C-
| | | | | |
H H H H H H
which is an absurdity because more than half of the carbon hands are
waving wildly around asking to be held by something. Benzene,
C_{6}H_{6}, evidently is like hexane, C_{6}H_{14}, in having a chain of
six carbon atoms, but it has dropped its H's like an Englishman. Eight
of the H's are missing.
Public-domain text, read in full here on John Shaqi.
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