Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Now one of the men who was worried over this benzene puzzle was the
German chemist, Kekule. One evening after working over the problem all
day he was sitting by the fire trying to rest, but he could not throw
it off his mind. The carbon and the hydrogen atoms danced like imps on
the carpet and as he watched them through his half-closed eyes he
suddenly saw that the chain of six carbon atoms had joined at the ends
and formed a ring while the six hydrogen atoms were holding on to the
outside hands, in this fashion:
H
|
C
/ \\
H-C C-H
|| |
H-C C-H
\ //
C
|
H
Professor Kekule saw at once that the demons of his subconscious self
had furnished him with a clue to the labyrinth, and so it proved. We
need not suppose that the benzene molecule if we could see it would look
anything like this diagram of it, but the theory works and that is all
the scientist asks of any theory. By its use thousands of new compounds
have been constructed which have proved of inestimable value to man. The
modern chemist is not a discoverer, he is an inventor. He sits down at
his desk and draws a "Kekule ring" or rather hexagon. Then he rubs out
an H and hooks a nitro group (NO_{2}) on to the carbon in place of it;
next he rubs out the O_{2} of the nitro group and puts in H_{2}; then he
hitches on such other elements, or carbon chains and rings as he likes.
He works like an architect designing a house and when he gets a picture
of the proposed compounds to suit him he goes into the laboratory to
make it. First he takes down the bottle of benzene and boils up some of
this with nitric acid and sulfuric acid. This he puts in the nitro group
and makes nitro-benzene, C_{6}H_{5}NO_{2}. He treats this with hydrogen,
which displaces the oxygen and gives C_{6}H_{5}NH_{2} or aniline, which
is the basis of so many of these compounds that they are all commonly
called "the aniline dyes." But aniline itself is not a dye. It is a
colorless or brownish oil.
It is not necessary to follow our chemist any farther now that we have
seen how he works, but before we pass on we will just look at one of his
products, not one of the most complicated but still complicated enough.
[Illustration: A molecule of a coal-tar dye]
The name of this is sodium ditolyl-disazo-beta-naphthylamine-
6-sulfonic-beta-naphthylamine-3.6-disulfonate.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account