Further light has been thrown on the act of crystallisation by another
most interesting research of Miers concerning “vicinal faces,”[21] such
as the three very low pyramid faces (forming a very flat triakis
octahedron) which often replace each octahedron face on a crystal of
alum which has been grown somewhat rapidly. The author has frequently
observed this phenomenon in the course of the numerous crystallisations
required for the investigation of the sulphates and selenates. It may be
described in general terms as the replacement of primary faces
possessing the simplest rational indices by faces having such high
indices that it is doubtful whether they ought really to be represented
by indices at all. The number of such vicinal faces which replace the
simple face depends on the symmetry of the crystal, to which, of course,
they conform. Thus, while three such vicinal faces replace an octahedral
face, and two replace the face of a tetragonal prism, the simple primary
prism face of a rhombic or monoclinic crystal would only be replaced by
one, which may have a deformation of as much as even 30′ from the
correct position of the prism face, and on either side of it. Indeed it
is possible for a whole succession of such vicinal faces to be developed
within the degree of arc which may in extreme cases separate the
limiting values on each side of the prism face, and such are often seen
and make up the well-known bundle of images afforded on the goniometer
by a bad face, a face which would cause the author at once to reject the
whole crystal for measurement purposes. One of the faces, even in cases
such as alum or a tetragonal crystal, where three or two might have
equal values as regards the symmetry, generally predominates, and
affords a very much more brilliant image of the goniometer signal than
the others in the bundle, so that an unwary observer might easily come
to the conclusion that this was the really valid image corresponding to
the octahedron face or to the simple primary prism face, or whatever
particular face was expected in the neighbourhood indicated by the
bundle of images. Obviously, however, it might only be one of three or
two equally valid faces of a vicinal form, which had grown
predominatingly during the last period of growth previous to removal
from the mother liquor.
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