Miers explains the appearance of the latter instead of octahedral faces
by assuming that the supersaturated liquid in contact with the growing
crystal consists of the particles (molecules) of salt uniformly mingled
with those of water, the solvent, and that the act of crystallisation
consists of the escape of the water and solidification of the salt.
Consequently, the salt particles just before crystallisation cannot be
so dense as they are along primary planes of the crystal, as they are
separated by the water particles, which are presumably much more
numerous. Hence it is that they are not deposited along the planes of
high reticular density, but along vicinal planes of low density of
points. For instance, he shows that the shower of salt particles upon a
cube face would have to be so dense that there would be insufficient
room for the water particles. The density in a cube face is 114 times as
great as that in one of the vicinal planes observed. Now, 100 cubic
centimetres of solid alum weigh 172 grammes, and 100 c.c. of the
solution depositing crystals contain 9·74 grammes of alum. Thus the
density of the growing crystal of alum is nearly 18 times that of the
alum in the adjacent saturated solution.
Consequently the deposition of the salt particles, in a moderately quick
crystallisation, when insufficient time is afforded for the deliberate
escape of the water particles and for the orderly rearrangement of the
salt particles, occurs along vicinal planes instead of along the primary
planes. For it must not be forgotten that whenever it has the
opportunity of coming into operation there is a directive molecular
force of some kind, which controls the operation of crystallisation, and
which undoubtedly attempts to cause, and given adequate time and scope
succeeds in causing, the production of faces of high reticular density,
the fundamentally important primary faces of lowest indices, and which
are often those along which cleavage occurs. Wulff emphasises this in
saying (_loc. cit._, p. 461): “Bei der Krystallisation orientiren sich
die Molekeln auf den Flächen des Krystalles ganz gleichförmig durch den
Einfluss der Richtkraft der Krystallisation.” The more rapidly the
crystallisation occurs, however, the less chance is there for this force
to attain its ultimate object. More will be said about this directive
force in the next chapter, after we have studied the remarkable “liquid
crystals” discovered by Lehmann.
Public-domain text, read in full here on John Shaqi.
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