An instance of a mineral with tetrahedral _molécules intégrantes_ Haüy
gives in tourmaline, and the primitive form of tourmaline he considered
to be a rhombohedron, conformably to the well-known rhombohedral
cleavage of the mineral, made up of six tetrahedra. Again, hexagonal
structures formed by three prismatic cleavage planes inclined at 60° are
considered by him as being composed of _molécules intégrantes_ of the
form of 60° triangular prisms, or _molécules soustractives_ of the shape
of 120° rhombic prisms, each of the latter being formed by two
_molécules intégrantes_ situated base to base. This will be clear from
Figs. 13 and 14, the former representing the structure as made up of
equilateral prismatic structural units, and the latter portraying the
same structure but composed of 120°-parallelepipeda by elimination of
one cleavage direction; each unit in the latter case possesses double
the volume of the triangular one, and being of parallelepipedal section
is capable of producing secondary faces when arranged step-wise, whereas
the triangular structure is not. The points at the intersections in
these diagrams should for the present be disregarded; they will shortly
be referred to for another purpose.
[Illustration:
FIG. 14.
]
Probably, the most permanent and important of Haüy’s achievements was
the discovery of the law of rational indices. At first this only took
the form of the observation of the very limited number of rows of
_molécules intégrantes_ or _soustractives_ suppressed. In introducing it
on page 74 of his 1784 “Essai” he says: “_Quoique je n’aie observé
jusqu’ici que des décroissemens qui se sont par des soutractions d’une
ou de deux rangées de molécules, et quelquefois de trois rangées, mais
très rarement, il est possible qu’il se trouve des crystaux dans
lesquels il y ait quatre ou cinq rangées de molécules supprimées à
chaque décroissement, et même un plus grand nombre encore. Mais ces cas
me semblent devoir être plus rares, à proportion que le nombre des
rangées soutraites sera plus considérable. On conçoit donc comment le
nombre des formes secondaires est néçessairement limité._”
The essential difference between Haüy’s views and our present ones,
which will be explained in Chapter IX., is that Haüy takes cleavage
absolutely as his guide, and considers the particles, into which the
ultimate operation of cleavage divides a crystal, as the solid
structural units of the crystal, the unit thus having the shape of at
least the _molécule intégrante_. Now every crystalline substance does
not develop cleavage, and others only develop it along a single plane,
or along a couple of planes parallel to the same direction, that of
their intersection and of the axis of the prism which two such cleavages
would produce, and which prism would be of unlimited length, being
unclosed.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account