dioxide, under which it can no longer remain liquid, but must become a
gas, the bubble disappears and the cavity becomes filled with gas.
Carbonic acid cavities are readily recognised, inasmuch as the bubble is
extremely mobile, and is normally in a state of movement on the very
slightest provocation.
[Illustration:
_PLATE IX._
FIG. 34.—Liquid Cavities in quartz Crystal (Trigonal) containing
Saturated Solution and Cubic Crystals of Sodium Chloride.
]
[Illustration:
FIG. 36.—Two characteristic Forms of Snow Crystals (Trigonal).
]
[Illustration:
FIG. 35.—Negative Ice Crystals, or “Water Flowers,” in Ice.
]
The liquid cavity in the remarkable quartz crystal illustrated in Fig.
34, and the bubble of vapour formed on cooling, and consequent
contraction of the liquid more than the solid quartz (the thermal
dilatation of liquids being usually greater than that of solids) when it
was no longer able to fill the cavity, remind one of the beautiful water
flowers formed for the contrary reason in ice on passing a beam of light
through a slab, owing to the warming effect of the accompanying heat
rays. Water crystallises like quartz, in the trigonal system, its normal
forms being the hexagonal prism and the rhombohedron. A slab of lake ice
is generally a huge crystal plate perpendicular to the trigonal axis, or
in the case of disturbed growth an interlacing mass of such crystals,
all perpendicular to the optic axis, the axis of the hexagonal prism and
of trigonal symmetry. When the heat rays from the lantern pass through
such a slab of ice, the surface of which is focussed on the screen by a
projecting lens, they cause the ice to begin to melt in numerous spots
in the interior of the slab simultaneously; and the structure of the
crystal is revealed by the operation occurring with production of
cavities taking the shape of hexagonal stars, which when focussed appear
on the screen as shown in Fig. 35. They are filled with water except for
a bubble (vacuole), which contains only water vapour. For the liquid
water occupies less room than did the ice from which it was produced,
owing to the well-known fact that water expands on freezing. This
abnormal expansion with cooling begins at the temperature of the maximum
density of water, 4° C., and proceeds steadily until the freezing point
0° is reached, when, at the moment of crystallisation, the mass suddenly
increases in volume by as much as 10 per cent. This expansive leap when
the molecules of water marshal themselves into the organised order of
the homogeneous structure, that of the space-lattice of the trigonal
(rhombohedral) system, is one of the most remarkable phenomena in
nature, and its exceptional character, so contrary to the usual
contraction on solidification of a liquid, is of vital moment to aquatic
life. For the layer of ice formed, being lighter than water, floats on
the surface of the latter, and thus forms a protective layer and
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