Detection of the Common Food Adulterants — John Shaqi
Detection of the Common Food AdulterantsBruce, Edwin M.
Science
Detection of the Common Food Adulterants
Bruce, Edwin M.
Food adulteration and inspection
_Mohler’s Test._--Treat the remainder of the second part of the above
ether residue with 2 or 3 cc. of concentrated sulfuric acid. Heat till
white fumes appear. Add a few crystals of potassium nitrate and when
cool dilute with water. Add an excess of ammonia, then a drop or two of
ammonium sulfid. If a red color appears immediately on the surface, it
shows the presence of benzoic acid.
COLORING MATTER IN CATSUPS AND TOMATOES
COCHINEAL
_Girard and Dupre Test._--Shake well a portion of the sample with water
and filter, acidify with hydrochloric acid, then extract with amyl
alcohol, and if cochineal is present the extract will be colored yellow
or orange, the particular shade depending on the amount of cochineal
present. Remove the amyl alcohol and wash with water until it is
neutral. To half of this, add a very dilute solution of uranium acetate,
drop by drop, and shaking well after the addition of each drop.
Cochineal, if present, will produce a characteristic emerald-green
color.
Confirm by adding a drop or two of ammonia to the second half of the
amyl alcohol extract and a violet coloration will be produced if
cochineal is present.
COAL-TAR COLORING MATTER
_Sostegni and Carpentieri Test._--Free from grease a piece of woolen
cloth (nun’s veiling will do) by boiling first in very dilute caustic
soda solution and then in water. Acidify a portion of the sample with 2
to 4 cc. of 10 per cent solution of hydrochloric acid and filter. Strips
of the cleansed cloth are boiled in this filtrate for 5 or 10 minutes,
then removed, washed in water and boiled with very dilute hydrochloric
acid solution. Wash out the acid and dissolve the color from the cloth
by boiling in a solution of ammonium hydroxid (1 to 50). (The time
required will depend upon the dye present.) Remove the cloth from the
solution and acidify the latter with hydrochloric acid and another piece
of the cleansed cloth is immersed and again boiled. This second dyeing
fixes only coal-tar colors on the cloth, hence, no fear of mistaking
them for the natural color of the vegetable.
IN GREEN PICKLES, BEANS, PEAS, ETC.
COPPER SALTS
Burn 20 grams of the sample to an ash and wet the ash with concentrated
nitric acid, dilute with water and boil. Add ammonia till strongly
alkaline and filter. If the filtrate is blue, copper is present.
Confirm by acidifying the filtrate with acetic acid and adding potassium
ferrocyanid. A red or brownish precipitate or coloration proves the
presence of copper. The test for other heavy metals may be made by the
general method given under meats.
IN MIXED PICKLES
TURMERIC
Shake with alcohol to extract the color. Soak a piece of filter paper in
the extract and dry in an air oven at 100° C. Wet the filter paper with
a weak solution of boric acid to which a very little hydrochloric acid
has been added. If turmeric is present, a cherry-red color will appear
when the filter paper is dry.
“SOAKED” VEGETABLES
PEAS, BEANS, AND CORN
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