Detection of the Common Food AdulterantsBruce, Edwin M.
Science
Detection of the Common Food Adulterants
Bruce, Edwin M.
Food adulteration and inspection
_Preliminary Test._--Treat the sample with strong hydrochloric acid, and
if tropæolin or methyl orange be present the solution will turn pink;
Martius yellow partially decolorizes the solution; dinitrocresols
decolorizes the solution. Turmeric or naphthol yellow produces no color
change.
TURMERIC
Turmeric may be detected by soaking a piece of filter paper in the
sample, drying and dipping it in a dilute solution of boric acid or
borax which has been slightly acidulated with hydrochlorid acid. Dry
again and a cherry-red color forms if turmeric is present. Add a drop of
dilute alkali and if turmeric be present the paper will be colored dark
olive.
COAL-TAR COLORS
Evaporate some of the extract to dryness; take up the residue with water
and extract the coal-tar colors if present, and test for them by the
method given under canned vegetables.
VANILLA EXTRACTS
The best grades of vanilla extract are made by treating vanilla beans
with 50 per cent alcohol. Coumarin, an extract from tonka beans, may be
used in making the extract. This of course would make a cheaper product.
If less than 50 per cent alcohol is used in making the extract, some
alkali must be added to dissolve the resins which will not dissolve in
a weaker alcohol. In artificial extracts some such coloring matter as
caramel or tannin is used.
_Preliminary Test._--To a portion of the extract add a few drops of lead
acetate solution. The absence of a bulky flocculent precipitate shows
the extract not to be of high quality. Leach recommends that normal
acetate of lead be added to the sample, and if a precipitate does not
form it is conclusive evidence that it is not a pure extract.
When a precipitate forms with the above reagent, it should settle
immediately and leave a clear and almost colorless liquid. When there is
a mere cloudiness only, it may be due to caramel, in which case the
extract is to be suspected.
ALKALI
Shake a portion of the sample with twice its volume of water. If no
precipitate forms, an alkali is present. A flocculent reddish-brown
precipitate shows no alkali is present. If the solution is milky it
indicates the presence of a foreign resin.
Add hydrochloric acid drop by drop to the diluted extract. Nothing more
than a mere turbidity should result. Should it be quite turbid and the
color fading after a time, it shows that an alkali has been used.
FOREIGN RESINS
Mix a portion of the extract slowly with twice its volume of water,
frequently shaking the mixture. When this solution is milky, it
indicates a foreign resin.
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