Detection of the Common Food AdulterantsBruce, Edwin M.
Science
Detection of the Common Food Adulterants
Bruce, Edwin M.
Food adulteration and inspection
_Pontet’s Test; Elaiden Test._--Treat 1 cc. of mercury with 12 cc. of
cold nitric acid (sp. gr. 1.42) and shake 2 cc. of this freshly-made
solution with 50 cc. of the sample in a bottle every 10 minutes for 2
hours. Oils which are principally olein, or mixtures of olein and solid
esters like palmatin and stearin, give more or less solid products, but
olive oil is remarkable for the firmness of the canary or lemon-yellow
mass which is formed. After standing a day the mass cannot be pierced
with a glass rod and sometimes it gives forth a sound when struck.
This test requires considerable experience to be used with any great
degree of certainty.
COTTONSEED OIL
Carbon bisulfid containing 1 per cent of sulfur in solution is mixed
with an equal amount of amyl alcohol. Equal volumes (about 3 cc.) of
this reagent and the sample, are mixed in a test tube, which is loosely
stoppered with cotton, and heated in a bath of boiling saturated brine
for a quarter of an hour. The presence of cottonseed oil is shown by the
formation of a deep-red or orange color. Little if any color is produced
in its absence. If no color is produced it is well to add another cc. of
the reagent and heat 5 or 10 minutes more, and to repeat this again if
no color forms. Lard and lard oil from animals fed on cottonseed meal
may give a faint reaction.
PEANUT OIL (ARACHIS OIL)
_Bellier’s Test._--Saponify a gram of the sample with 5 cc. of a
solution of 85 grams potassium hydroxid in a liter of strong alcohol.
This may be done in a small Erlenmeyer flask on the water-bath. Then
boil for two minutes, neutralize exactly with dilute acetic acid (use
phenolphthalein as the indicator). Cool the mixture by placing the flask
in water at 17° to 19° C. A precipitate usually forms. Add 50 cc. of 70
per cent alcohol which contains one per cent by volume of concentrated
hydrochloric acid (sp. gr. 1.2). Shake the flask vigorously and cool
again as before. If no precipitate forms the oil is not adulterated with
peanut oil. The presence of 10 per cent or more of peanut oil produces a
precipitate, even a smaller amount will produce a cloudiness after
standing between 17° and 19° C. for 30 minutes.
Some varieties of olive oil from Tunis give the same turbidity when the
70 per cent alcohol is added. To distinguish these from peanut oil heat
the mixture on the water-bath till everything has dissolved, and cool to
17° to 19°. The cloudiness will not appear if the oil is pure, but will
reappear if peanut oil is present.
SESAME OIL
_Badouin’s Test._--About 0.1 of a gram of cane sugar is dissolved in 10
cc. of hydrochloric acid (sp. gr. 1.20) shaken vigorously with 20 grams
of the sample for a minute or more. After standing for a while the
aqueous solution will separate from the oil. If 1 per cent or more of
sesame oil is present, the aqueous solution will be colored crimson.
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