Detection of the Common Food AdulterantsBruce, Edwin M.
Science
Detection of the Common Food Adulterants
Bruce, Edwin M.
Food adulteration and inspection
It is very difficult to identify beef-stearin by chemical tests. It is
usually detected by use of the microscope. Leach gives the following
method: Make a solution of 2 to 5 grams of the fat in 10 to 20 cc. of
ether. Let stand a half day, at about the room temperature. Loosely
stopper the tube with cotton to prevent too rapid evaporation of the
ether. It is well to vary the conditions of heat, amount of solvent, and
rate of crystallization, to get the best possible results. It may often
be well to separate the crystals thus obtained by filtering and
recrystallizing from ether. Separate the crystals that form at the
bottom of the test tube from the liquid portion by pouring on a small
filter. Wash them several times with ether, but not sufficient to remove
the mother liquor entirely. In case it is all removed, and the crystals
are too fragile to mount, add a drop of alcohol. Crystals of lard
stearin are flat rhomboidal plates, one end being oblique to the sides,
and they do not appear to be regularly grouped. Beef-stearin crystals
are rod-shaped, or needles often apparently curved with pointed ends,
and are arranged in clusters like the ribs of a fan, the crystals
radiating from a common point. Under certain conditions the lard
crystals are not irregularly grouped, but are arranged like the parts of
a feather, where one part seems attached to another close at hand.
Considerable experience is necessary to use this test with absolute
certainty.
OLIVE OIL
Olive oil is one of the most commonly adulterated foods. The commonest
adulterant probably is cottonseed oil. Other foreign oils, such as
peanut, sesame, and rape, are sometimes used.
_Preliminary Test._--Pure olive oil turns from a pale to a dark-green
color in a few minutes, when it is shaken with the same volume of
concentrated nitric acid or sulfuric acid. Whenever a reddish to an
orange, or brown coloration results, the presence of a foreign vegetable
oil is indicated (probably a seed oil).
Bach gives the following results of strong nitric acid on the common
oils. Olive oil when shaken with nitric acid gives a pale green, which
changes to an orange yellow after heating five minutes. With similar
treatment peanut oil gives pale rose and brownish yellow; rape oil, pale
rose and orange yellow; sesame oil, white and brownish yellow; sunflower
oil, dirty white and reddish yellow; cottonseed oil, yellowish brown and
reddish brown; castor oil, pale rose and golden yellow.
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