Detection of the Common Food AdulterantsBruce, Edwin M.
Science
Detection of the Common Food Adulterants
Bruce, Edwin M.
Food adulteration and inspection
_Mohler’s Method._--Prepare a sample as in the test for salicylic acid
by heating 50 grams of the meat in 50 cc. of water. Add 10 cc. of a
concentrated solution of glacial phosphoric acid, and strain through a
cotton bag. Neutralize with sodium hydrate and evaporate to dryness or
to a small volume. After treating with 3 cc. of concentrated sulfuric
acid, heat till white fumes appear. Add 4 or 5 crystals of potassium
nitrate and continue heating until the solution is colorless or nearly
so. When cool dilute with water, add an excess of ammonia, and place in
a narrow vessel like a test tube. Add one or two drops of ammonium
sulfid carefully so that the liquids do not mix. If the surface of the
liquid immediately becomes red, benzoic acid is present.
If this test is not carefully performed, it is worthless, as other
substances give similar results.
Confirm its presence by neutralizing the aqueous solution of the
extracted benzoic acid with sodium hydroxid; concentrate to a very small
volume. Acidify with sulfuric acid. A white flocculent precipitate shows
the presence of considerable benzoic acid.
CANNED MEAT
If in preparing canned meat only fresh meat is used, there is little
need for the use of preservatives, but as considerable smoked and cured
meat is thus used, preservatives may find their way into canned meat.
The same preservatives should be looked for as in fresh and smoked meat
and the same test made for each.
HEAVY METALS
_A. H. Allen’s Method._--About 25 grams of the substance is mixed slowly
with enough strong, pure sulfuric acid to just moisten the mass,
avoiding an excess. Heat on a water-bath for a short time, then raise
the temperature gradually, and maintain till the chlorids seem to be
decomposed. It must not be hot enough, however, to volatilize the
sulfuric acid. Then add 1 cc. of strong nitric acid and heat till red
fumes are given off. Freshly ignited magnesia in the proportion of 0.5
gram for each cc. of sulfuric and nitric acid previously used is now
stirred into the mass and the whole ignited at a dull red heat. This is
best done in a gas-muffle. When cool, moisten the ash with nitric acid
and gently re-ignite, repeating this treatment till the carbon is
entirely consumed. Treat the residue with 8 or 10 drops of strong
sulfuric acid, heat till fumes are given off, cool, boil with water,
dilute to about 100 cc. and saturate with hydrogen sulfid, filter,
examine as follows:
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