Determination of the Atomic Weight of Cadmium and the Preparation of Certain of Its Sub-CompoundsJones, Harry C. (Harry Clary)
Science
Determination of the Atomic Weight of Cadmium and the Preparation of Certain of Its Sub-Compounds
Jones, Harry C. (Harry Clary)
Atomic weights; Cadmium; Thesis (Ph. D.)
The polyhedral aggregates were abundant and reached considerable
dimensions. The crystallizing power of the cadmium however, seems to be
less, so that the only crystals suitable for measurement were extremely
minute. The largest individuals were barrel-shaped, like those of zinc
and resembled little piles of basal plates. Their side planes are not
infrequently uneven and bent, probably as the result of the softness
and great ductility of the metal.
Only the most minute crystals show pyramidal planes of comparative
perfection. These are well suited for a microscopic examination, but
their small size renders their measurement on a reflecting goniometer
a matter of difficulty. After a careful search two crystals were
secured which, although they had a diameter of only one third of a
millimeter, from their microscopic appearances promised good results.
Their planes however were found to give compound reflections and a
somewhat disappointing variation in corresponding angles. On the best
crystal three zones were measured as follows: (normal angles)
Zone I Zone II Zone III
0001 : 01ī1 = 62° 35′ |0001 : 10ī1 = 62° 4′ |0001 : 1ī01 = 62° 29′
0001 : 01ī0 = 89° 50½′| |
0001 : 01īī = 118° 57′ |0001 : 10īī = 118° 28′|
The second crystal was much less satisfactory, since values for the
angle between the base and pyramid (0001): (01ī1) were obtained which
varied all the way from 61° 2′ to 63° 43′. These measurements must
therefore be regarded as of little or no value. If we average the
readings for this angle on the first crystal we obtain 62° 23′, from
which
̲a : ̲c = 1 : 1.6554.
A comparison of the axial ratios of the four rhombohedral and four
holohedral hexagonal elements gives the following:
{ Bismuth ̲a : ̲c = 1 : 1.3035 (G. Rose, 1849).
Rhombo- { Antimony ̲a : ̲c = 1 : 1.3235 (Laspeyres, 1875).
hedral. { Tellurium ̲a : ̲c = 1 : 1.3298 (G. Rose, 1849).
{ Arsenic ̲a : ̲c = 1 : 1.4025 (Zepharovich, 1875).
{ Zinc ̲a : ̲c = 1 : 1.356425 (Williams and
{ Burton, 1889).
Holohedral. { Beryllium ̲a : ̲c = 1 : 1.5802 (Brögger, 1884).
{ Magnesium ̲a : ̲c = 1 : 1.6202 (Williams, 1890).
{ Cadmium ̲a : ̲c = 1 : 1.6554 (Williams, 1891).
Zinc appears from its axial ratio to belong rather to the rhombohedral
group and this is the only one of the last four elements upon which the
faintest indication of any divergence from a holohedral development
of all of its forms has been observed. On crystals of this substance
there is an occasional rhombohedral alternative of the faces of
certain of the pyramids, although the crystals otherwise appear to be
holohedral.[19]
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