Determination of the Atomic Weight of Cadmium and the Preparation of Certain of Its Sub-Compounds — John Shaqi
Determination of the Atomic Weight of Cadmium and the Preparation of Certain of Its Sub-CompoundsJones, Harry C. (Harry Clary)
Science
Determination of the Atomic Weight of Cadmium and the Preparation of Certain of Its Sub-Compounds
Jones, Harry C. (Harry Clary)
Atomic weights; Cadmium; Thesis (Ph. D.)
von Hauer, Journ. f. prakt. Chem. 72, 338. 1857. His method consisted
in reducing a weighed amount of cadmium sulphate to the sulphide
in a stream of hydrogen sulphide, under pressure, at an elevated
temperature, and weighing the sulphide. The reduction was shown to be
complete by proving the absence of sulphate in the sulphide.
64.2051 grams of cadmium sulphate
gave 44.4491 ” ” ” sulphide.
If the atomic weight of oxygen = 16,
” ” ” ” ” sulphur = 32.059,
” ” ” ” cadmium = 111.935.
The atomic weight of cadmium calculated as an average of the nine
determinations made using the above values for oxygen and sulphur =
111.94.
Maximum, 112.121.
Minimum, 111.796.
Mean, 111.940.
The work of von Hauer is greatly to be preferred to that of Stromeyer.
The large amount of material used in each determination tended to
lessen any experimental error. A very considerable degree of care
seems to have been exercised in purifying the cadmium sulphate. In
determinations 1-5 a different specimen of sulphate was employed from
that in determinations 6-9. The average value found in the first
five determinations = 111.910, in the last four = 111.977. The close
agreement between the results obtained from the different preparations
of the sulphate argues in favor of a fair degree of purity for all the
material.
The method of weighing the more or less hygroscopic cadmium sulphate is
open to criticism when employed in accurate work. The cadmium sulphate
was placed in an open boat, dried, cooled over sulphuric acid, and
weighed. It was again dried, cooled as before, and weighed. The second
weighing could be quickly accomplished since the approximate weight
was known. The two weighings agreed to within less than a milligram
or a third drying and weighing were made. An error of a milligram
in the weight of the sulphate produced an average error in the atomic
weight of cadmium of about .06. That a discrepancy of greater or less
magnitude was introduced from this source will be readily seen.
Dumas Ann. Chim. Phys. 55, 158. 1859, determined the relation between
cadmium chloride and the metallic silver required to precipitate the
chlorine. Metallic cadmium was dissolved in boiling hydrochloric acid
and the solution evaporated. The cadmium chloride was fused for five or
six hours in a stream of hydrochloric acid gas. Six determinations were
made. 23.0645 grams of cadmium chloride were equivalent to 27.173 grams
of metallic silver.
If the atomic weight of silver = 107.93.
” ” ” ” ” chlorine = 35.45.
” ” ” ” cadmium = 112.322.
The atomic weight of cadmium calculated as the average of the six
determinations made, using the above values for silver and chlorine =
112.241.
Maximum, 112.759.
Minimum, 111.756.
Mean, 112.241.
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