After exposure for some time to the sun many diamonds glow in
a dark room. Some diamonds are fluorescent, appearing milky in
sunlight. In a vacuum, exposed to a high-tension current of
electricity, diamonds phosphoresce of different colours, most South
African diamonds shining with a bluish light. Diamonds from other
localities emit bright blue, apricot, pale blue, red, yellowish
green, orange, and pale green light. The most phosphorescent
diamonds are those which are fluorescent in the sun. One beautiful
green diamond in the writer’s collection, when phosphorescing in a
good vacuum, gives almost as much light as a candle, and you can
easily read by its rays. But the time has hardly come when diamonds
can be used as domestic illuminants! The emitted light is pale
green, tending to white, and in its spectrum, when strong, can be
seen bright lines, one at about λ 5370 in the green, one at λ 5130
in the greenish blue, and one at λ 5030 in the blue. A beautiful
collection of diamond crystals belonging to Professor Maskelyne
phosphoresces with nearly all the colours of the rainbow, the
different faces glowing with different shades of colour. Diamonds
which phosphoresce red generally show the yellow sodium line on
a continuous spectrum. In one Brazilian diamond phosphorescing a
reddish-yellow colour I detected in its spectrum the citron line
characteristic of yttrium.
The rays which make the diamond phosphoresce are high in the
ultra-violet. To illustrate this phosphorescence under the
influence of the ultra-violet rays, arrange a powerful source
of these rays, and in front expose a design made up of certain
minerals, willemite, franklinite, calcite, etc.--phosphorescing
of different colours. Their brilliant glow ceases entirely when a
thin piece of glass is interposed between them and the ultra-violet
lamp.
I now draw attention to a strange property of the diamond, which
at first sight might seem to discount the great permanence and
unalterability of this stone. It has been ascertained that the
cause of phosphorescence is in some way connected with the
hammering of the electrons, violently driven from the negative
pole on to the surface of the body under examination, and so great
is the energy of the bombardment, that impinging on a piece of
platinum or even iridium, the metal will actually melt. When the
diamond is thus bombarded in a radiant matter tube the result is
startling. It not only phosphoresces, but becomes discoloured,
and in course of time becomes black on the surface. Some diamonds
blacken in the course of a few minutes, while others require an
hour or more to discolour. This blackening is only superficial,
and although no ordinary means of cleaning will remove the
discolouration, it goes at once when the stone is polished with
diamond powder. Ordinary oxidising reagents have little or no
effect in restoring the colour.
[Illustration: FIG. 17. DIAMOND-CUT GLASS AND SHAVINGS.]
[Illustration: FIG. 18. DIAMONDS IN RÖNTGEN RAYS.
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