A. BLACK DIAMOND IN GOLD FRAME.
B. PINK DELHI DIAMOND.
C. PASTE IMITATION OF B.
To face p. 98.]
The superficial dark coating on a diamond after exposure to
molecular bombardment I have proved to be graphite. M. Moissan has
shown that this graphite, on account of its great resistance to
oxidising reagents, cannot have been formed at a lower temperature
than 3600° C.
It is thus manifest that the bombarding electrons, striking the
diamond with enormous velocity, raise the superficial layer to the
temperature of the electric arc and turn it into graphite, whilst
the mass of diamond and its conductivity to heat are sufficient to
keep down the general temperature to such a point that the tube
appears scarcely more than warm to the touch.
A similar action occurs with silver, the superficial layers of
which can be raised to a red heat without the whole mass becoming
more than warm.
CONVERSION OF DIAMOND INTO GRAPHITE
Although we cannot convert graphite into diamond, we can change
the diamond into graphite. A clear crystal of diamond is placed
between two carbon poles, and the poles with intervening diamond
are brought together and an arc formed between. The temperature of
the diamond rapidly rises, and when it approaches 3600° C., the
vaporising point of carbon, it breaks down, swells, and changes
into black and valueless graphite.
TRIBO-LUMINESCENCE
A few minerals give out light when rubbed. In the year 1663 the
Hon. Robert Boyle read a paper before the Royal Society, in which
he described several experiments made with a diamond which markedly
showed tribo-luminescence. As specimens of tribo-luminescent bodies
I may instance sphalerite (sulphide of zinc), and an artificial
sphalerite, which is even more responsive to friction than the
native sulphide.[6]
Mrs. Kunz, wife of the well-known New York mineralogist, possesses,
perhaps, the most remarkable of all phosphorescing diamonds. This
prodigy diamond will phosphoresce in the dark for some minutes
after being exposed to a small pocket electric light, and if rubbed
on a piece of cloth a long streak of phosphorescence appears.
ABSORPTION SPECTRUM OF DIAMOND
On passing a ray of light through a diamond and examining it in a
spectroscope, Walter has found in all colourless brilliants of over
1 carat in weight an absorption band at wave-length 4155 (violet).
He ascribes this band to an impurity and suggests it may possibly
be due to samarium. Three other fainter lines were detected in the
ultra-violet by means of photography.
REFRACTIVITY
Public-domain text, read in full here on John Shaqi.
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