Discoveries and Inventions of the Nineteenth CenturyRoutledge, Robert
History
Discoveries and Inventions of the Nineteenth Century
Routledge, Robert
Inventions -- History -- 19th century
nails in yet another way, we may proceed to subject them to a _chemical_
change, by an experiment very simple in itself, but involving certain
precautions, by neglect of which the tyro in chemical operations would
incur some personal risks; these might however be obviated by using only
very small quantities of the materials (a mere pinch of iron filings and
a few drops of sulphuric acid), when the results would still be
sufficiently observable. A few of the iron nails having been placed in a
flask of thin glass, we pour upon them a mixture of oil of vitriol
(sulphuric acid) and water, which has previously been prepared by
gradually adding 1 measure of the acid to 5 measures of water. The
action that takes place is greatly accelerated by heat, and indeed the
contents should be heated to boiling by standing the flask on a layer of
fine sand spread on an iron plate and gently heated from below. The
nails will soon disappear, being completely dissolved by the acid
liquid, and the turbid solution should be filtered through filtering
paper as rapidly as possible and while still hot. This turbid and dirty
looking condition is due to foreign matters in the nails, for these
never consist of _pure_ iron. The filtered liquid is set aside to cool
in a closed vessel, in which after a time will be found a deposit of
crystals of a pale bluish-green colour. The liquor above these having
been poured off, the crystals are to be rinsed with a very small
quantity of _cold_ water, and then dried between folds of
blotting-paper, after which they are ready for examination. The quantity
of the diluted acid put into the flask should have a certain proportion
to the weight of the nails; about 5 _fluid ounces_ to 1 ounce of iron
will be found convenient, for if less is used the nails will not be
entirely dissolved, and an excess will tend to keep the crystals in
solution instead of depositing them when cold. The nails—as such—will
now have passed out of existence: can we say that the iron that formed
them exists in the crystals? Certainly not as the _metal_ iron, for
every property of the metal will have disappeared. The crystals are
brittle, can be crushed in a mortar—they are translucent—they show no
metallic lustre, but only glassy surfaces—they are readily dissolved by
water—they are not attracted by a magnet. The most powerful lens will
fail to show the least particle of iron in them; they have in their
properties no assignable relation to the metal of the nails, but are
matter of quite another sort; and be it noted that this entire
_otherness_ is the special and characteristic sign of _chemical change_.
So complete is the transformation in the case we have been considering
that it would never have been said that iron was contained in these
crystals, but rather that the metal had for ever passed out of
existence, but for one circumstance; and that is, that by subjecting the
crystals to certain processes of _chemical analysis_ we can again obtain
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