Discoveries and Inventions of the Nineteenth CenturyRoutledge, Robert
History
Discoveries and Inventions of the Nineteenth Century
Routledge, Robert
Inventions -- History -- 19th century
We have seen how malleable iron or steely iron may be directly obtained
from the ores, but it has been found that on the large scale it is
necessary and more economical to operate on the pig iron produced by the
blast furnaces in such a manner as to remove the greater part of the
foreign substances.
[Illustration:
FIG. 19.—_Section of a Reverberatory Furnace._
]
The first step in the conversion of the pig iron usually taken has been,
and to a certain extent even is still, to remelt the metal in what is
termed a _finery furnace_, a kind of forge in which a charcoal fire is
urged by a cold blast, and so regulated that an excess of oxygen is
supplied, or rather more than would suffice to convert all the carbon of
the fuel into carbonic acid; although this is perhaps not absolutely
necessary, as carbonic acid would itself supply oxygen by suffering
reduction to carbonic oxide. At any rate the melted metal is exposed to
an oxidizing atmosphere and constantly stirred. Many different
arrangements of the furnace and details of the process have been used.
For instance, where the finest quality of malleable iron was not aimed
at, coke has been the fuel employed, and many shapes of furnaces, etc.,
have been contrived, and various additions of ores, oxides, etc., made
to the charge, according to local practice and the nature of the crude
iron. One marked effect of the operation is the final removal of nearly
all the _silicon_, which is burnt or oxidized into _silica_, and this at
once unites with oxide of iron, which is also formed, to produce a
readily fusible slag of silicate of iron, and in the production of this
silicate any sand attached to the pig will also take part. Much of the
carbon, amounting sometimes to more than half, is also eliminated as
carbonic oxide, and of what is left but little remains in the graphitic
state. The action on the phosphorus is usually less marked, but there is
always a notable reduction of the quantity. The sulphur is also lessened
in some degree, although when coke is used, the fuel has the
disadvantage of itself containing sulphur, phosphates, and other
deleterious matters. Sometimes a little lime is added to the charge to
take up the sulphur from the coke. The operation lasts some hours, the
fused metal being frequently stirred with an iron rod, until it assumes
a pasty granular condition, when the workman gradually collects it upon
the end of the rod into a ball of about three-quarters of a cwt. in
weight. These balls, or _blooms_ as they are called, are removed from
the furnace while still intensely hot, and at once submitted to powerful
pressure by means of some suitable mechanical arrangement, the effect
being to squeeze out the liquid slag and force the particles of metal
together by which the whole becomes partially welded into a more compact
mass. Then this mass is, while still hot, either hammered with gradually
increased force of the strokes, or in the more modern practice, passed
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