Discoveries and Inventions of the Nineteenth CenturyRoutledge, Robert
History
Discoveries and Inventions of the Nineteenth Century
Routledge, Robert
Inventions -- History -- 19th century
The most usual of the older processes of steel-making, still carried on
at Sheffield and elsewhere, is known as the _cementation process_: it
consists in heating bars of the best wrought iron in contact with
charcoal, at a high temperature, for three or four weeks. At Sheffield
the iron bars and charcoal are packed in alternate layers into troughs
14 ft. long by 3½ ft. deep and wide, constructed of slabs of siliceous
sandstone 6 in. thick. The last layer of charcoal at the top is covered
to a certain depth with a layer of refractory matter, and the flames
from a furnace beneath are made to envelop the stone troughs or _pots_,
as they are technically called, for a period of a week or more according
to the thickness of the bars operated upon. These are generally 3 in.
broad and from five- to six-eighths of an inch thick. When it is found
by withdrawing a test bar for examination that the operation is
complete, the fire is gradually diminished and the whole allowed to cool
slowly, which requires about a fortnight. Instead of only charcoal, a
mixture of powdered charcoal or soot with a little salt has been used by
some makers—which mixture, technically called _cement powder_, has given
its name to the process. In some works 16 tons or more of iron are
treated in one operation. The bars are found unchanged in form, but
increased in weight by perhaps 27 lbs. per ton, for carbon has combined
with the iron, being apparently transferred in the iron from one
particle to another. The surface of the bars becomes rough and uneven
from a multitude of blebs or blisters, and hence they are called
_blister bars_, and the steel of which they now consist is named
_blister steel_. In this conversion we may suppose that the iron at its
outer surface first enters into combination with carbon taken from the
carbonic oxide gas, which would be produced by combustion of the
charcoal with the limited quantity of air in its interstices, and the
oxygen thus set free would immediately seize again on the surrounding
charcoal, and by repeated changes of this kind in which the oxygen acts
as a carrier of carbon to the iron, in which it is transferred inwards
from particle to particle. The cause of the blisters has been much
discussed: probably the cause is the formation and escape of a volatile
compound of carbon and sulphur at the surface of the soft metal; for it
is known that nearly the whole of the little sulphur in the wrought iron
disappears in the cementation process. Blister steel is never
homogeneous, for near the surface it always contains more carbon than
within; the bars are therefore broken up into short lengths which are
carefully assorted, bound together with wire, heated, welded together
under a hammer or by rolling, and finally formed into a bar, which is
stamped with the outline of a pair of shears, and is then known as
_shear steel_, because this product was generally found the most
suitable for making the shears used in dressing cloth.
Public-domain text, read in full here on John Shaqi.
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