Discoveries and Inventions of the Nineteenth CenturyRoutledge, Robert
History
Discoveries and Inventions of the Nineteenth Century
Routledge, Robert
Inventions -- History -- 19th century
Now, as this heat is generated in the
interior of, and is diffused in innumerable fiery bubbles through, the
whole fluid mass, the metal absorbs the greater part of it, and its
temperature becomes immensely increased, and by the expiration of the
fifteen minutes before named that part of the carbon which appears
mechanically mixed and diffused throughout the crude iron has been
entirely consumed: the temperature however is so high that the
chemically combined carbon now begins to separate from the metal, as is
at once indicated by an immense increase in the volume of flame rushing
out of the throat of the vessel. The metal in the vessel now rises
several inches above its natural level, and a light frothy slag makes
its appearance and is thrown out in large foam-like masses. This violent
eruption of cinder generally lasts about five or six minutes, when all
further appearance of it ceases, a steady and powerful flame replacing
the shower of sparks and cinder which always accompanies the boil. The
rapid union of carbon and oxygen which thus takes place adds still
further to the temperature of the metal, while the diminished quantity
of carbon present allows a part of the oxygen to combine with the iron,
which undergoes combustion and is converted into an oxide. At the
excessive temperature that the metal has now acquired, the oxide as soon
as formed undergoes fusion, and forms a powerful solvent of those earthy
bases that are associated with the iron; the violent ebullition which is
going on mixes most intimately the scoria and metal, every part of which
is thus brought in contact with the fluid oxide, which will thus wash
and cleanse the metal most thoroughly from the silicon and other earthy
bases which are combined with the crude iron, while the sulphur and
other volatile matters which cling so tenaciously to iron at ordinary
temperatures are driven off, the sulphur combining with the oxygen and
forming sulphurous acid gas.
“The loss in weight of crude iron during its conversion into an ingot of
malleable iron was found, on a mean of four experiments, to be 12½ per
cent., to which will have to be added the loss of metal in the finishing
rolls. This will make the entire loss probably not less than 18 per
cent. instead of about 28 per cent., which is the loss on the present
system. A large portion of this metal is however recoverable by heating
with carbonaceous gases the rich oxides thrown out of the furnace during
the boil. These slags are found to contain innumerable small grains of
metallic iron, which are mechanically held in suspension in the slags
and may be easily recovered.
Public-domain text, read in full here on John Shaqi.
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