[Footnote B: "Das Brennbare."]
It may also be seen from the above experiments, that a given quantity of
air can only unite with, and at the same time saturate, a certain
quantity of the inflammable substance: this is evident from the 9th
paragraph, _letter b_. But whether the phlogiston which was lost by the
substances was still present in the air left behind in the bottle, or
whether the air which was lost had united and fixed itself with the
materials such as liver of sulphur, oils, &c., are questions of
importance.
From the first view, it would necessarily follow that the inflammable
substance possessed the property of depriving the air of part of its
elasticity, and that in consequence of this it becomes more closely
compressed by the external air. In order now to help myself out of these
uncertainties, I formed the opinion that any such air must be
specifically heavier than ordinary air, both on account of its
containing phlogiston and also of its greater condensation. But how
perplexed was I when I saw that a very thin flask which was filled with
this air, and most accurately weighed, not only did not counterpoise an
equal quantity of ordinary air, but was even somewhat lighter. I then
thought that the latter view might be admissible; but in that case it
would necessarily follow also that the lost air could be separated again
from the materials employed. None of the experiments cited seemed to me
capable of shewing this more clearly than that according to the 10th
paragraph, because this residuum, as already mentioned, consists of
vitriolated tartar and alkali. In order therefore to see whether the
lost air had been converted into fixed air, I tried whether the latter
shewed itself when some of the caustic ley was poured into lime water;
but in vain--no precipitation took place. Indeed, I tried in several
ways to obtain the lost air from this alkaline mixture, but as the
results were similar to the foregoing, in order to avoid prolixity I
shall not cite these experiments. Thus much I see from the experiments
mentioned, that the air consists of two fluids, differing from each
other, the one of which does not manifest in the least the property of
attracting phlogiston, while the other, which composes between the third
and the fourth part of the whole mass of the air, is peculiarly disposed
to such attraction. But where this latter kind of air has gone to after
it has united with the inflammable substance, is a question which must
be decided by further experiments, and not by conjectures.
We shall now see how the air behaves towards inflammable substances when
they get into fiery motion. We shall first consider that kind of fire
which does not give out during the combustion any fluid resembling air.
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