+17. First Experiment.+--I placed 9 grains of phosphorus from urine in a
thin flask, which was capable of holding 30 ounces of water, and closed
its mouth very tightly. I then heated, with a burning candle, the part
of the flask where the phosphorus lay; the phosphorus began to melt, and
immediately afterwards took fire; the flask became filled with a white
cloud, which attached itself to the sides like white flowers; this was
the dry acid of phosphorus. After the flask had become cold again, I
held it, inverted, under water and opened it; scarcely had this been
done when the external air pressed water into the flask; this water
amounted to 9 ounces.
+18. Second Experiment.+--When I placed pieces of phosphorus in the same
flask and allowed it to stand, closed, for 6 weeks, or until it no
longer glowed, I found that 1/3 of the air had been lost.
+19. Third Experiment.+--I placed 3 teaspoonfuls of iron filings in a
bottle capable of holding 2 ounces of water; to this I added an ounce of
water, and gradually mixed with them half an ounce of oil of vitriol. A
violent heating and fermentation took place. When the froth had somewhat
subsided, I fixed into the bottle an accurately fitting cork, through
which I had previously fixed a glass tube A (Fig. 1). I placed this
bottle in a vessel filled with hot water, B B (cold water would greatly
retard the solution). I then approached a burning candle to the orifice
of the tube, whereupon the inflammable air took fire and burned with a
small yellowish-green flame. As soon as this had taken place, I took a
small flask C, which was capable of holding 20 ounces of water, and held
it so deep in the water that the little flame stood in the middle of the
flask. The water at once began to rise gradually into the flask, and
when the level had reached the point D the flame went out. Immediately
afterwards the water began to sink again, and was entirely driven out of
the flask. The space in the flask up to D contained 4 ounces, therefore
the fifth part of the air had been lost. I poured a few ounces of lime
water into the flask in order to see whether any aerial acid had also
been produced during the combustion, but I did not find any. I made the
same experiment with zinc filings, and it proceeded in every way
similarly to that just mentioned. I shall demonstrate the constituents
of this inflammable air further on; for, although it seems to follow
from these experiments that it is only phlogiston, still other
experiments are contrary to this.
We shall now see the behaviour of air towards that kind of fire which
gives off, during the combustion, a fluid resembling air.
[Illustration: _Fig. 1._]
[Illustration: _Fig. 2._]
[Illustration: _Fig. 3._]
[Illustration: _Fig. 4._]
[Illustration: _Fig. 5._]
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