+20. Fourth Experiment.+--It is well known that the flame of a candle
absorbs air; but as it is very difficult, and, indeed, scarcely
possible, to light a candle in a closed flask, the following experiment
was made in the first place:--I set a burning candle in a dish full
water; I then placed an inverted flask over this candle; at once there
arose from the water large air bubbles, which were caused by the
expansion, by heat, of the air in the flask. When the flame became
somewhat smaller, the water began to rise in the flask; after it had
gone out and the flask had become cold, I found the fourth part filled
with water. This experiment was very undecisive to me, because I was not
assured whether this fourth part of the air had not been driven out by
the heat of the flame; since necessarily in that case the external air
resting upon the water seeks equilibrium again after the flask has
become cold, and presses the same measure of water into the flask as of
air had been previously driven out by the heat. Accordingly, I made the
following experiment:
+21. Fifth Experiment.+--(_a._) I pressed upon the bottom of the dish A
(Fig. 2) a tough mass, of the thickness of two fingers, made of wax,
resin, and turpentine metal together; in the middle I fastened a thick
iron wire which reached to the middle of the flask B; upon the point of
this wire C, I stuck a small wax candle, whose wick I had twisted
together out of three slender threads. I then lighted the candle, and at
the same time placed over it the inverted flask B, which I then pressed
very deep into the mass. As soon as this was done, I filled the dish
with water. After the flame was extinguished and everything had become
quite cold, I opened the flask in the same position under the water,
when 2 ounces of water entered; the flask held 160 ounces of water.
Accordingly, there is wanting here so much air as occupies the space of
2 ounces of water. Has this air been absorbed by the inflammable
substance, or has the heat of the small flame driven it out even before
I could press the flask into the tough mass? The latter seems to have
taken place in this case, as I conclude from the following:--I took a
small flask capable of holding 20 ounces of water; in this I caused a
candle to burn as in the preceding; after everything had become cold, I
opened this flask likewise under water, whereupon similarly nearly 2
ounces entered. Had the former 2 ounces measure of air been absorbed,
then there should have been only 2 drachms measure absorbed in this
experiment.
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