Dyes and dyeingPellew, Charles E. (Charles Ernest), Viscount Exmouth
Science
Dyes and dyeing
Pellew, Charles E. (Charles Ernest), Viscount Exmouth
Dyes and dyeing
For the second, or fixing, bath—that is, the alkali bath—it is now
customary to use a solution of soda instead of the extract made
from wood ashes. Either cooking soda (bicarbonate of soda) or the
stronger washing soda or soda crystals, known to the chemist as
carbonate of soda, will be satisfactory, and instead of soda the
corresponding potash salts may be used, though these are usually
more expensive. It is possible, too, to use a bath of the so-called
caustic soda, or caustic potash, known to the chemist as hydroxide of
soda and hydroxide of potash. But these, as the name implies, must
be handled with care because, when strong, they are likely to burn
the hands and clothes. Careful analyses of dyed mummy cloths show
that the ancient Egyptians were accustomed to use for their second or
fixing bath, a solution of slaked lime, or lime water.
_Khaki._—By mixing in the first bath of copperas or other iron salt
an equal quantity of chrome alum, and then fixing and developing as
above, a certain amount of greenish chromium oxide is deposited in
the fibre along with the oxide of iron. This gives rise to the shade
known as “khaki.” Sometimes shaded a little with manganese brown,
this was the regular dye for the army uniforms, until the recent
introduction of the extremely fast and very satisfactory vat dyes.
_Uses._—Iron buff is chiefly used for cotton, linen, and other
vegetable fabrics; on them it gives pleasant, warm shades of orange
and reddish-brown. But on wool, and especially on silk, it is not so
satisfactory, owing to its tendency to roughen and injure the fibre.
Indeed, in the case of silk, it is likely to greatly diminish, or
even to destroy, the lustre. On cotton and linen, however, it has
great fastness to light and to washing. Indeed, every one who has
tried to get rust stains out of a garment or a piece of table linen
knows how hard a matter it is to get rid of the color.
Another important reason for using this dye is that the coloring
agents are very cheap, and are easily obtained in any quantities.
It has, however, some serious disadvantages, one of which is that
the color, especially in dark shades, is very liable to rub. This
can best be obviated by building up the shades with successive
dippings; and by thoroughly washing the finished goods in a hot soap
bath. The dyed goods are pretty certain to be a little stiff, and
therefore hard to sew or cut, owing to the fact that the final color
is composed of iron rust. When vegetable fibres are filled with a
mineral matter they are naturally stiffer and harder than they were
originally.
Public-domain text, read in full here on John Shaqi.
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