Dyes and dyeingPellew, Charles E. (Charles Ernest), Viscount Exmouth
Science
Dyes and dyeing
Pellew, Charles E. (Charles Ernest), Viscount Exmouth
Dyes and dyeing
The discovery was made accidentally, by a young chemical student,
William Henry Perkin, while experimenting in a very crude and simple
way, with a view to forming artificial quinine from a curious oily
body known as aniline. This aniline was originally prepared by
distilling indigo in a dry retort, and it had received its name from
the native Javanese word “anil,” meaning indigo. While thus prepared
it was, of course, very expensive. But about this time methods were
invented for obtaining this same compound in practically unlimited
quantities from coal tar—that heavy, foul-smelling refuse of gas
works—which, up to that time, had been not only useless but actually
a source of annoyance and expense to the gas companies.
Perkin conceived the idea that, by partially burning or oxidizing
it, this aniline might be changed into quinine. He made the
experiment and there resulted a black molasses-like mass, very far
removed from the white crystals he was hoping for. But by testing
this with various chemicals, he found that hot alcohol dissolved
part of it, and turned it into a violet liquid which had the power
to dye silk and wool the same bright color. Finding that the color
was fairly fast to light, and that it could be produced without too
much expense, he took out a patent and, with the aid of his father
and brother, set up near Manchester, England, the first factory for
artificial dyestuffs.
His discoveries were at once published, and chemists all over the
world began to manufacture and experiment with the new dyestuffs.
Great factories were started all over Europe. From this beginning the
manufacture of coal-tar dyestuffs, and more recently all their allied
compounds, has become one of the most important and most profitable
of all chemical industries.
The dyes first discovered, the so-called “Basic dyes,” were of great
brilliancy and strength; but they were not of any particular beauty
when used individually. Compared with the vegetable colors which
preceded them, and especially the same shades we are accustomed
to see in nature, these dyes were hard, coarse, crude, and very
inartistic. This could be remedied, however, by mixing two or three
of them together, such mixture tending to soften the different colors
and blend all into pleasant and delicate shades.
A more serious difficulty was the fact that those early dyestuffs
were usually quite fugitive to light or, at any rate, far less fast
than the best of the vegetable dyes that preceded them. Besides, they
did not fade true. In other words, a piece of cloth might to-day be
a bright red, and after a few days of exposure to the sunlight, the
exposed portions might turn a yellow, a white, or even some dark
color; and, in any case, the change would entirely spoil the original
color scheme.
Public-domain text, read in full here on John Shaqi.
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