Dyes and dyeingPellew, Charles E. (Charles Ernest), Viscount Exmouth
Science
Dyes and dyeing
Pellew, Charles E. (Charles Ernest), Viscount Exmouth
Dyes and dyeing
The first efforts in this direction were based upon the saving of
some or, indeed, nearly all, of the gum which is wasted in the
stripping or degumming process previously described. This gum,
which amounts to from 20 to 35 per cent. of the raw silk, makes the
silk stiff in texture and dull in color and more difficult to dye.
Accordingly, in former years, it was invariably washed out of the
silk with the greatest care before any attempt was made to dye it.
But by modifying the dyeing, and especially the finishing process,
it was found possible to produce the so-called “souples”—i.e., silks
with little or no lustre, but with the characteristic “scroop” or
“feel”—capable of replacing bright silk as a filling in many fabrics
and yet containing almost all the natural gum left in the fibre.
The black silks were then attacked and an elaborate system of
mordanting was introduced before the dyeing proper began. For
instance, the silk can be steeped alternately in one solution after
another, first of iron salts and then of ferrocyanide of potash, thus
forming Prussian blue in the fibre. Then the excess of iron can be
converted by immersion in tannin solutions, such as Gambier or Cutch,
into black tannate of iron, or ink, and finally, after perhaps a
light bath in chromium salts, the real black color is brought out by
boiling in logwood extract. The silk is then brightened by boiling
with good neutral Castile soap, is shaded, if necessary, by dyeing
with either an Acid or Basic dye in a weak bath, and, after drying
and finishing, the finished product may easily weigh two or even
three times as much as the original raw silk, and still retain its
strength, lustre, and elasticity.
_Tin Weighting._—The weighting of colored and bright silks did not
proceed so rapidly, and it was not much more than ten years ago that,
by accident, some French dyers discovered that by immersion in a
strong bath of tin chloride (stannic chloride acidified with some
hydrochloric acid) the silk fibre would absorb a large percentage
of tin salts without necessarily losing lustre, dyeing capacity, or
even strength. This at first was kept a secret, but its use gradually
spread, until now it is a very poor silk dyer who cannot weight his
silk 100 or 150 per cent. without spoiling its immediate commercial
value.
Without going into unnecessary details, the process is somewhat as
follows: The silk, after being degummed and thoroughly washed free of
soap, is plunged into a bath of tin chloride and kept there for some
hours. It is then taken out and the loose tin salts are washed off in
a tank of water (technically called a box), or in a washing machine.
To further “set” the tin, the silk is then placed for a short time
in a solution of phosphate of soda and again washed thoroughly. It
has now gained from 15 to 25 per cent of its original weight (2½ to 4
ounces to the pound of raw silk).
Public-domain text, read in full here on John Shaqi.
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