If we had two large water tanks, one of which could be emptied only
by allowing the bottom to fall completely out, and the other by means
of a narrow pipe, it is easy to see which would be the more useful to
us as a source of water supply. If both tanks were filled, then from
the first we could get only a sudden uncontrollable rush of water,
but from the other we could get a steady stream extending over a long
period, and easily controlled. The Leyden jar stores electricity,
but in yielding up its store it acts like the first tank, giving a
sudden discharge in the form of a bright spark. We cannot control the
discharge, and therefore we cannot make it do useful work for us. For
practical purposes we require a storing arrangement that will act like
the second tank, giving us a steady current of electricity for a long
period, and this we have in the accumulator or storage cell.
A current of electricity has the power of decomposing certain liquids.
If we pass a current through water, the water is split up into its
two constituent gases, hydrogen and oxygen, and this may be shown by
the apparatus seen in Fig. 12. It consists of a glass vessel with two
strips of platinum to which the current is led. The vessel contains
water to which has been added a little sulphuric acid to increase its
conducting power, and over the strips are inverted two test-tubes
filled with the acidulated water. The platinum strips, which are
called _electrodes_, are connected to a battery of Daniell cells.
When the current passes, the water is decomposed, and oxygen collects
at the electrode connected to the positive terminal of the battery,
and hydrogen at the other electrode. The two gases rise up into the
test-tubes and displace the water in them, and the whole process is
called the electrolysis of water. If now we disconnect the battery and
join the two electrodes by a wire, we find that a current flows from
the apparatus as from a voltaic cell, but in the opposite direction
from the original battery current.
[Illustration: FIG. 12.--Diagram showing Electrolysis of Water.]
It will be remembered that one of the troubles with a simple voltaic
cell was polarization, caused by the accumulation of hydrogen; and that
this weakened the current by setting up an opposing electro-motive
force tending to produce another current in the opposite direction.
In the present case a similar opposing or back electro-motive force
is produced, and as soon as the battery current is stopped and the
electrodes are connected, we get a current in the reverse direction,
and this current continues to flow until the two gases have recombined,
and the electrodes have regained their original condition. Consequently
we can see that in order to electrolyze water, our battery must have an
electro-motive force greater than that set up in opposition to it, and
at least two Daniell cells are required.
Public-domain text, read in full here on John Shaqi.
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