This apparatus thus may be made to serve to some extent as an
accumulator or storage cell, and it also serves to show that an
accumulator does not store up or accumulate electricity. In a voltaic
cell we have chemical energy converted into electrical energy, and here
we have first electrical energy converted into chemical energy, and
then the chemical energy converted back again into electrical energy.
This is a rough-and-ready way of putting the matter, but it is good
enough for practical purposes, and at any rate it makes it quite clear
that what an accumulator really stores up is not electricity, but
energy, which is given out in the form of electricity.
The apparatus just described is of little use as a source of current,
and the first really practical accumulator was made in 1878 by Gaston
Planté. The electrodes were two strips of sheet lead placed one upon
the other, but separated by some insulating material, and made into a
roll. This roll was placed in dilute sulphuric acid, and one strip or
plate connected to the positive, and the other to the negative terminal
of the source of current. The current was passed for a certain length
of time, and then the accumulator partly discharged; after which
current was passed again, but in the reverse direction, followed by
another period of discharge. This process, which is called _forming_,
was continued for several days, and its effect was to change one plate
into a spongy condition, and to form a coating of peroxide of lead on
the other. When the plates were properly formed the accumulator was
ready to be fully charged and put into use. The effect of charging was
to rob one plate of its oxygen, and to transfer this oxygen to the
other plate, which thus received an overcharge of the gas. During the
discharge of the accumulator the excess of oxygen went back to the
place from which it had been taken, and the current continued until the
surfaces of both plates were reduced to a chemically inactive state.
The accumulator could be charged and discharged over and over again as
long as the plates remained in good order.
In 1881, Faure hit upon the idea of coating the plates with a paste of
red-lead, and this greatly shortened the time of forming. At first it
was found difficult to make the paste stick to the plates, but this
trouble was got rid of by making the plates in the form of grids, and
pressing the paste into the perforations. Many further improvements
have been made from time to time, but instead of tracing these we will
go on at once to the description of a present-day accumulator. There
are now many excellent accumulators made, but we have not space to
consider more than one, and we will select that known as the “Chloride”
accumulator.
Public-domain text, read in full here on John Shaqi.
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