Elements of Chemistry,: In a New Systematic Order, Containing all the Modern DiscoveriesLavoisier, Antoine Laurent
Science
Elements of Chemistry,: In a New Systematic Order, Containing all the Modern Discoveries
Lavoisier, Antoine Laurent
Chemistry -- Early works to 1800
But, to determine the specific gravity of air or of gasses, and to
ascertain their weight in a known volume, it is necessary to know their
temperature, as well as the degree of pressure under which they subsist;
and this is accomplished by means of a small thermometer, strongly
cemented into a brass collet, which screws into the lid of the jar A.
This thermometer is represented separately, Pl. VIII. Fig. 10. and in
its place 24, 25, Fig. 1. and Pl. IX. Fig. 4. The bulb is in the inside
of the jar A, and its graduated stalk rises on the outside of the lid.
The practice of gazometry would still have laboured under great
difficulties, without farther precautions than those above described.
When the jar A sinks in the water of the cistern LMNO, it must lose a
weight equal to that of the water which it displaces; and consequently
the compression which it makes upon the contained air or gas must be
proportionally diminished. Hence the gas furnished, during experiments
from the machine, will not have the same density towards the end that it
had at the beginning, as its specific gravity is continually
diminishing. This difference may, it is true, be determined by
calculation; but this would have occasioned such mathematical
investigations as must have rendered the use of this apparatus both
troublesome and difficult. Mr Meusnier has remedied this inconvenience
by the following contrivance. A square rod of iron, 26, 27, Pl. VIII.
Fig. 1. is raised perpendicular to the middle of the beam DE. This rod
passes through a hollow box of brass 28, which opens, and may be filled
with lead; and this box is made to slide alongst the rod, by means of a
toothed pinion playing in a rack, so as to raise or lower the box, and
to fix it at such places as is judged proper.
When the lever or beam DE stands horizontal, this box gravitates to
neither side; but, when the jar A sinks into the cistern LMNO, so as to
make the beam incline to that side, it is evident the loaded box 28,
which then passes beyond the center of suspension, must gravitate to the
side of the jar, and augment its pressure upon the included air. This is
increased in proportion as the box is raised towards 27, because the
same weight exerts a greater power in proportion to the length of the
lever by which it acts. Hence, by moving the box 28 alongst the rod 26,
27, we can augment or diminish the correction it is intended to make
upon the pressure of the jar; and both experience and calculation show
that this may be made to compensate very exactly for the loss of weight
in the jar at all degrees of pressure.
Public-domain text, read in full here on John Shaqi.
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