Elements of Chemistry,: In a New Systematic Order, Containing all the Modern DiscoveriesLavoisier, Antoine Laurent
Science
Elements of Chemistry,: In a New Systematic Order, Containing all the Modern Discoveries
Lavoisier, Antoine Laurent
Chemistry -- Early works to 1800
Before beginning any experiment, the closeness of the luting ought
always to be previously tried, either by slightly heating the retort A,
Pl. IV. Fig. 1, or by blowing in a little air by some of the
perpendicular tubes S s s s; the alteration of pressure causes a
change in the level of the liquid in these tubes. If the apparatus be
accurately luted, this alteration of level will be permanent; whereas,
if there be the smallest, opening in any of the junctures, the liquid
will very soon recover its former level. It must always be remembered,
that the whole success of experiments in modern chemistry depends upon
the exactness of this operation, which therefore requires the utmost
patience, and most attentive accuracy.
It would be of infinite service to enable chemists, especially those who
are engaged in pneumatic processes, to dispense with the use of lutes,
or at least to diminish the number necessary in complicated instruments.
I once thought of having my apparatus constructed so as to unite in all
its parts by fitting with emery, in the way of bottles with cristal
stoppers; but the execution of this plan was extremely difficult. I have
since thought it preferable to substitute columns of a few lines of
mercury in place of lutes, and have got an apparatus constructed upon
this principle, which appears capable of very convenient application in
a great number of circumstances.
It consists of a double necked bottle A, Pl. XII. Fig. 12.; the interior
neck bc communicates with the inside of the bottle, and the exterior
neck or rim de leaves an interval between the two necks, forming a
deep gutter intended to contain the mercury. The cap or lid of glass B
enters this gutter, and is properly fitted to it, having notches in its
lower edge for the passage of the tubes which convey the gas. These
tubes, instead of entering directly into the bottles as in the ordinary
apparatus, have a double bend for making them enter the gutter, as
represented in Fig. 13. and for making them fit the notches of the cap
B; they rise again from the gutter to enter the inside of the bottle
over the border of the inner mouth. When the tubes are disposed in their
proper places, and the cap firmly fitted on, the gutter is filled with
mercury, by which means the bottle is completely excluded from any
communication, excepting through the tubes. This apparatus may be very
convenient in many operations in which the substances employed have no
action upon Mercury. Pl. XII. Fig. 14. represents an apparatus upon this
principle properly fitted together.
Mr Seguin, to whose active and intelligent assistance I have been very
frequently much indebted, has bespoken for me, at the glass-houses, some
retorts hermetically united to their recipients, by which luting will be
altogether unnecessary.
CHAP. VIII.
_Of Operations upon Combustion and Deflagration._
SECT. I.
_Of Combustion in general._
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