Elements of Chemistry,: In a New Systematic Order, Containing all the Modern DiscoveriesLavoisier, Antoine Laurent
Science
Elements of Chemistry,: In a New Systematic Order, Containing all the Modern Discoveries
Lavoisier, Antoine Laurent
Chemistry -- Early works to 1800
It is very probable that water is decomposed during the deflagration of
gun-powder, and that part of the oxygen furnished to the nascent
carbonic acid gas is produced from it. If so, a considerable quantity of
hydrogen gas must be disengaged in the instant of deflagration, which
expands, and contributes to the force of the explosion. It may readily
be conceived how greatly this circumstance must increase the effect of
powder, if we consider that a pint of hydrogen gas weighs only one
grain and two thirds; hence a very small quantity in weight must occupy
a very large space, and it must exert a prodigious expansive force in
passing from the liquid to the aeriform state of existence.
In the last place, as a portion of undecomposed water is reduced to
vapour during the deflagration of gun-powder, and as water, in the state
of gas, occupies seventeen or eighteen hundred times more space than in
its liquid state, this circumstance must likewise contribute largely to
the explosive force of the powder.
I have already made a considerable series of experiments upon the nature
of the elastic fluids disengaged during the deflagration of nitre with
charcoal and sulphur; and have made some, likewise, with the oxygenated
muriat of potash. This method of investigation leads to tollerably
accurate conclusions with respect to the constituent elements of these
salts. Some of the principal results of these experiments, and of the
consequences drawn from them respecting the analysis of nitric acid, are
reported in the collection of memoirs presented to the Academy by
foreign philosophers, vol. xi. p. 625. Since then I have procured more
convenient instruments, and I intend to repeat these experiments upon a
larger scale, by which I shall procure more accurate precision in their
results; the following, however, is the process I have hitherto
employed. I would very earnestly advise such as intend to repeat some of
these experiments, to be very much upon their guard in operating upon
any mixture which contains nitre, charcoal, and sulphur, and more
especially with those in which oxygenated muriat of potash is mixed with
these two materials.
Public-domain text, read in full here on John Shaqi.
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