Elements of Chemistry,: In a New Systematic Order, Containing all the Modern DiscoveriesLavoisier, Antoine Laurent
Science
Elements of Chemistry,: In a New Systematic Order, Containing all the Modern Discoveries
Lavoisier, Antoine Laurent
Chemistry -- Early works to 1800
I had formally advanced, in my first Memoirs upon the formation of
water, that it was decomposed in a great number of chemical experiments,
and particularly during the vinous fermentation. I then supposed that
water existed ready formed in sugar, though I am now convinced that
sugar only contains the elements proper for composing it. It may be
readily conceived, that it must have cost me a good deal to abandon my
first notions, but by several years reflection, and after a great number
of experiments and observations upon vegetable substances, I have fixed
my ideas as above.
I shall finish what I have to say upon vinous fermentation, by
observing, that it furnishes us with the means of analysing sugar and
every vegetable fermentable matter. We may consider the substances
submitted to fermentation, and the products resulting from that
operation, as forming an algebraic equation; and, by successively
supposing each of the elements in this equation unknown, we can
calculate their values in succession, and thus verify our experiments by
calculation, and our calculation by experiment reciprocally. I have
often successfully employed this method for correcting the first results
of my experiments, and to direct me in the proper road for repeating
them to advantage. I have explained myself at large upon this subject,
in a Memoir upon vinous fermentation already presented to the Academy,
and which will speedily be published.
FOOTNOTES:
[26] The above apparatus is described in the Third Part.--A.
CHAP. XIV.
_Of the Putrefactive Fermentation._
The phenomena of putrefaction are caused, like those of vinous
fermentation, by the operation of very complicated affinities. The
constituent elements of the bodies submitted to this process cease to
continue in equilibrium in the threefold combination, and form
themselves anew into binary combinations[27], or compounds, consisting
of two elements only; but these are entirely different from the results
produced by the vinous fermentation. Instead of one part of the hydrogen
remaining united with part of the water and charcoal to form alkohol, as
in the vinous fermentation, the whole of the hydrogen is dissipated,
during putrefaction, in the form of hydrogen gas, whilst, at the same
time, the oxygen and charcoal, uniting with caloric, escape in the form
of carbonic acid gas; so that, when the whole process is finished,
especially if the materials have been mixed with a sufficient quantity
of water, nothing remains but the earth of the vegetable mixed with a
small portion of charcoal and iron. Thus putrefaction is nothing more
than a complete analysis of vegetable substance, during which the whole
of the constituent elements is disengaged in form of gas, except the
earth, which remains in the state of mould[28].
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