Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
As soon as the matters contained in the alembic grow hot, vapours begin
to arise from them, and ascending through the neck of the alembic into
the head, are by the sides thereof stopped and condensed: from thence
they trickle down in little streams to the groove, which conveys them
to the spout; and by that they pass out of the alembic into a glass
vessel with a long neck, the end of the spout being introduced into
that neck, and luted thereto.
To facilitate the refrigeration and condensation of the vapours
circulating in the head, all alembics of metal are moreover provided
with another piece, which is a kind of large pan of the same metal,
fitted and soldered round the head. This piece serves to keep cold
water in, which incessantly cools the head, and therefore it is called
the _Refrigeratory_. The water in the refrigeratory itself grows hot
after some time, and must therefore be changed occasionally; the heated
water being first drawn off by means of a cock fixed near the bottom of
the refrigeratory. All copper alembics should be tinned on the inside
for the reasons already given.
When saline spirits are to be distilled, alembics of metal must not
be used; because the saline vapours would corrode them. In this case
recourse must be had to alembics of glass. These consist of two pieces
only; namely, a _Cucurbit_, whose superior orifice is admitted into and
exactly luted with its _Head_, which is the second piece.
In general, as alembics require that the vapours of the matter to be
distilled should rise to a considerable heighth, they ought to be used
only when the most volatile principles are to be drawn from bodies:
and the lighter and more volatile the substances to be separated by
distillation are, the taller must the alembic be; because the most
ponderous parts, being unable to rise above a certain heighth, fall
back again into the cucurbit as soon as they arrive there, leaving the
lighter to mount alone, whose volatility qualifies them to ascend into
the head.
When a matter is to be distilled, that requires a very tall alembic,
and yet does not admit of a metalline vessel, the end will be best
answered by a glass vessel of a round or oval shape, having a very
long neck, with a small head fitted to its extremity. Such a vessel
serves many purposes: it is sometimes employed as a receiver, and at
other times as a digesting vessel; on which last occasion it goes under
the name of a _Matrass_. When one of these, provided with a head, is
applied to the purpose of distilling, it forms a sort of alembic.
Public-domain text, read in full here on John Shaqi.
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