Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Lastly, others are of opinion that this Acid is no other than the
universal or Vitriolic Acid; disguised indeed by a portion of the
Phlogiston, which is combined with it in a peculiar manner by the means
of putrefaction. They ground this opinion chiefly on the analogy or
resemblance which they find between the Nitrous Acid and the Volatile
Sulphureous Spirit. Its volatility, its pungent smell, its properties
of taking fire, and of destroying the blue and violet colours of
vegetables, serve them as so many proofs.
Their opinion is the more probable on this account, that even though
the Nitrous Acid should actually be produced by vegetable and animal
substances, yet as these substances themselves draw all their component
principles from the earth, and as the Vitriolic Acid is diffused
through all the soils which afford them nourishment, there is great
reason to think that the Nitrous Acid is no other than the Vitriolic
Acid altered by the changes and combinations it hath undergone in its
passage into and through those substances. In 1750 the Royal Academy
of Sciences at Berlin proposed an account of the generation of Nitre
as the subject for their prize, which was conferred on a Memoir
wherein this last opinion was supported by some new and very judicious
experiments.
The process by which our Salt-petre makers extract Nitre in quantities,
out of rubbish and nitrous earths, is very nearly the same with that
here set down; so that I shall not enter into a particular account
of it. I shall only take notice of one thing, which it is of some
consequence to know; namely, that there is no nitrous earth which does
not contain sea-salt also. The greatest quantities of this salt are to
be found in those earths which have been drenched with urine, or other
animal excrements. Now as the rubbish of old houses in great cities
is in this class, it comes to pass that when the Salt-petre workers
evaporate a nitrous lixivium drawn from that rubbish, as soon as the
evaporation is brought to a certain pitch, a great many little crystals
of sea-salt form in the liquor, and fall to the bottom of the vessel.
The Salt-petre workers in France call these saline particles _the
Grain_, and take care to separate them from the liquor (which, as
long as it continues hot, keeps the salt-petre dissolved) before they
set it to crystallize. This fact seems a little singular, considering
that sea-salt dissolves in water more easily than salt-petre, and
crystallizes with more difficulty.
Public-domain text, read in full here on John Shaqi.
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