Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
In order to discover the cause of this phenomenon, we must recollect
some truths delivered in our theoretical Elements. The first is, that
water can keep but a determinate quantity of any salt in solution, and
that if water fully saturated with a salt be evaporated, a quantity
of salt will crystallize in proportion to the quantity of water
evaporated. The second is, that those salts which are the most soluble
in water, particularly those which run in the air, will dissolve in
cold and in boiling water equally; whereas much greater quantities of
the other salts will dissolve in hot and boiling water than in cold
water. These things being admitted, when we know that sea-salt is
one of the first sort, and salt-petre of the second, the reason why
sea-salt precipitates in the preparation of salt-petre appears at once.
For,
When the solution of Salt-petre and Sea-salt comes to be evaporated to
such a degree that it contains as much Sea-salt as it possibly can,
this salt must begin to crystallize, and continue to do so gradually
as the evaporation advances. But because at the same time it does not
contain as much salt-petre as it can hold, seeing it is capable of
dissolving a much greater quantity thereof when it is boiling hot than
when it is cold, this last-named salt will not crystallize so soon. If
the evaporation were continued till the case of the Salt-petre came to
be the same with that of the Sea-salt, then the salt-petre also would
begin to crystallize gradually in proportion to the water evaporated,
and the two salts will continue crystallizing promiscuously together:
but it is never carried so far; nor is it ever necessary: for, as the
water cools, it becomes more and more incapable of holding in solution
the same quantity of salt-petre as when it was boiling hot.
And then comes the very reverse, with regard to the crystallizing of
the two salts; for then the Salt-petre shoots, and not the Sea-salt.
The reason of this fact also is founded on what has just been said. The
Sea-salt, of which cold water will dissolve as much as boiling water,
and which owed its crystallizing before only to the evaporation, now
ceases to crystallize as soon as the evaporation ceases; while the
Salt-petre, which the water kept dissolved only because it was boiling
hot, is forced to crystallize merely by the cooling of the water.
Public-domain text, read in full here on John Shaqi.
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