Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
"As they ascend with great rapidity, the little hole must be frequently
opened, to observe whether the hissing be not too strong: for, in that
case, it would be necessary to shut the door of the ash-hole quite
close. These white vapours continue two hours. When you find they cease
rising, make a small passage through the dome, by opening
some of its registers, that the flame may just begin to draw. Keep up
the fire in this mean state till the first volatile Phosphorus begin to
appear.
"This appears in about three hours after the white vapours first begin
to rise. In order to discover it, pull out the little birchen peg once
every minute, and rub it against some hot part of the furnace, where it
will leave a trail of light, if there be any Phosphorus upon it.
"Soon after you observe this sign, there will issue out through the
little hole of the ballon a stream of blueish light, which continues of
a greater or shorter extent to the end of the operation. This stream or
spout of light does not burn. If you hold your finger against it for
twenty or thirty seconds, the light will adhere to it; and if you rub
that finger over your hand, the light will besmear it, and render it
luminous.
"But from time to time this streamer darts out to the length of seven
or eight inches, snapping and emitting sparks of fire; and then it
burns all combustible bodies that come in its way. When you observe
this, you must manage the fire very warily, and shut the door of the
ash-hole quite close, yet without ceasing to throw coals into the
fire-place every two minutes.
"The Volatile Phosphorus continues two hours; after which the little
spout of light contracts to the length of a line or two: and now is the
time for pushing your fire to the utmost: immediately set the door of
the ash-hole wide open, throw billets of wood into it, unstop all the
registers of the reverberatory, supply the fire-place with large coals
every minute: in short, for six or seven hours all the inside of the
furnace must be kept of a white heat, so that the retort shall not be
distinguishable.
"In this fierce extremity of heat the true Phosphorus distils like an
oil, or like melted wax: one part thereof floats on the water in the
recipient, the other falls to the bottom. At last, the operation is
known to be quite over when the upper part of the ballon, in which the
volatile Phosphorus appears condensed in a blackish film, begins to
grow red: for this shews that the Phosphorus is burnt where the red
spot appears. You must now stop all the registers, and shut all the
doors of the furnace, in order to smother the fire; and then close
up the little hole in the ballon with fat lute or bees-wax. In this
condition the whole must be left for two days; because, the vessels
must not be separated till they are perfectly cold, lest the Phosphorus
should take fire.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account