Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
"As soon as the fire is out, the ballon, which is then in the dark,
presents a most agreeable object: all the empty part thereof above
the water seems filled with a beautiful blue light: which continues
for seven or eight hours, or as long as the ballon keeps warm, never
disappearing till it is cooled.
"When the furnace is quite cold take out the vessels, and separate them
from each other as neatly as possible. With a linen cloth wipe away
all the black stuff you find in the mouth of the ballon; for if that
filth should mix with the Phosphorus, it would hinder it from being
transparent when moulded. This must be done with great expedition:
after which pour into the ballon two or three quarts of cold water, to
accelerate the precipitation of the Phosphorus that swims at top. Then
agitate the water in the ballon, to rinse out all the Phosphorus that
may stick to the sides: pour out all the water thus shaken and turbid,
into a very clean earthen pan, and let it stand till it grows clear.
Then decant this first useless water, and on the blackish sediment,
left at the bottom of the pan, pour some boiling water to melt the
Phosphorus; which thereupon unites with the fuliginous matter, or
volatile Phosphorus, that precipitated with it, both together forming a
mass of the colour of slate. When this water, in which you have melted
the Phosphorus, is cool enough, take out the Phosphorus, throw it into
cold water, and therein break it into little bits in order to mould it.
"Then take a matras, having a long neck somewhat wider next the body
than at its mouth: cut off half the body, so as to make a funnel of
the neck-part, the smaller end of which must be stopped with a cork.
The first mould being thus prepared, plunge it endwise, with its
mouth uppermost, in a vessel full of boiling water, and fill it with
that water. Into this funnel throw the little bits of your slate-like
mass, which will melt again in this hot water, and fall so melted to
the bottom of the tube. Stir this melted matter with an iron wire, to
promote the separation of the Phosphorus from the fuliginous matter
with which it is fouled, and which, being less ponderous than the
Phosphorus, will gradually rise above it towards the upper part of the
cylinder.
Public-domain text, read in full here on John Shaqi.
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