Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
"Keep the water in the vessel as hot as at first, till, on taking out
the tube, you see the Phosphorus clean and transparent. Let the clear
tube cool a little, and then set it in cold water, where the Phosphorus
will congeal as it cools. When it is perfectly congealed, pull out the
cork, and with a small rod, near as big as the tube, push the cylinder
of Phosphorus towards the mouth of the funnel, where the feculency
lies. Cut off the black part of the cylinder, and keep it apart: for
when you have got a quantity thereof, you may melt it over again in the
same manner, and separate the clean Phosphorus which it still contains.
As to the rest of the cylinder which is clean and transparent, if you
intend to mould it into smaller cylinders, you may cut it in slices,
and melt it again by the help of boiling water in glass tubes of
smaller dimensions."
_OBSERVATIONS._
This process for making Phosphorus is copied from the Memoirs of the
Academy of Sciences for the Year 1737; where it is described by M.
Hellot, with so much accuracy, clearness, and precision, that I thought
I could not do better than transcribe it, without departing from the
author's own expressions, for the sake of such as may not have those
Memoirs. We shall take occasion, in these observations, to point out
some essential circumstances which I have omitted in the description
of the Process, that I might not break the connection between the
phenomena that happen in the course of this experiment.
It is proper to observe, in the first place, that one of the most usual
causes of miscarriage in this operation is a defect of the requisite
qualities in the retort employed. It is absolutely necessary to have
that vessel made of the best earth, and so well made that it shall be
capable of resisting the utmost violence of fire, continued for a very
long time; as appears by the description of the process. The retorts
commonly sold by potters, and other earthen-ware men, are not fit for
this operation; and M. Hellot was obliged to send to Hesse-Cassel for
such as he wanted.
Public-domain text, read in full here on John Shaqi.
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