Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
We shall, in the second place, observe with M. Hellot, that, "before
you set your retort in the furnace, it is proper to make an essay of
your matter, to see if there be reason to hope for success. For this
purpose put about an ounce thereof into a small crucible, and heat it
till the vessel be red. The mixture, after having smoked, ought to chop
or crack without puffing up, or even rising in the least. From these
cracks will issue undulating flames, white and blueish, darting upwards
with rapidity. This is the first volatile Phosphorus, which occasions
all the danger of the operation. When these first flashes are over,
increase the heat of your matter by laying a large live coal upon the
crucible. You will then see the second Phosphorus, like a luminous,
steady vapour, of a colour inclining to violet, covering the whole
surface of the matter: it continues for a very long time, and diffuses
a smell of garlic, which is the distinguishing odour of the Phosphorus
you are seeking.
"When this luminous vapour is entirely gone, pour the red hot matter
out of the crucible upon an iron plate. If you do not find one drop of
salt in fusion, but that, on the contrary, the whole falls readily into
powder, it is a proof that your matter was sufficiently lixiviated, and
that it contains no more fixed Salt, or Sea-salt, if you will, than
is requisite. If you find on the plate a drop of salt coagulated, it
shews that there is too much left in, and that there is danger of your
miscarrying in the operation; because the redundant salt would corrode,
and eat through the retort. In this case your matter must be washed
again, and then sufficiently dried."
Our third observation shall be concerning the furnace proper to be
employed in this operation. This furnace must be so constructed, that,
within a narrow compass it may give a heat at least equal to that of
a glass-house furnace, or rather greater, especially during the last
seven or eight hours of the operation. M. Hellot in his Memoir gives an
exact description of such a furnace.
"As certain accidents may happen in the course of the operation, some
precautions are to be taken against them. For instance, if the ballon
should break while the Phosphorus is distilling, and any of it should
fall on combustible bodies, it would set them on fire, and probably
burn the laboratory, because it is not to be extinguished without the
greatest difficulty. The furnace must therefore be erected under some
vault, or upon a bed of brick-work raised under some chimney that draws
well: nor must any furniture or utensil of wood be left near it. If a
little flaming Phosphorus should fall on a man's legs or hands, in less
than three minutes it would burn its way to the very bone. In such a
case nothing but urine will stop its progress.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account