Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Sea-Salt, as hath been already said, is a Neutral Salt composed of an
Acid, which differs from those of Vitriol and Nitre, combined with a
fixed Alkali that has some peculiar properties; but does not vary from
the others in its affinities. This Salt therefore, as well as Nitre,
must be decomposed by the Vitriolic Acid; which accordingly is the
case in the process here described. The Vitriolic Acid unites with the
Alkaline basis of the Sea-salt, and separates its Acid; and that with
much greater facility than it expels the Nitrous Acid from its Alkaline
basis, because the Acid of Sea-salt has not so great an affinity as the
Nitrous Acid with Fixed Alkalis.
As a highly concentrated Oil of Vitriol is used on this occasion, and
as the Sea-salt is previously dried and decrepitated, the Acid obtained
from it by distillation is very free from phlegm, and always smokes,
even more violently than the strongest Acid of Nitre. The vapours of
this Acid are also much more elastic and more penetrating than those
of the Nitrous Acid: on which account this distillation of the smoking
Spirit of Salt is one of the most difficult, most laborious, and most
dangerous operations in Chymistry.
This process requires a tubulated retort, that the Oil of Vitriol
may be mixed with the Sea-salt after the receiver is well luted to
the retort, and not before: for, as soon as these two matters come
together, the Spirit of Salt rushes out with so much impetuosity, that,
if the vessels were not luted at the time, the copious vapours that
would issue through the neck of the ballon would so moisten it, as well
as the neck of the retort, that it would be impracticable to apply the
lute and secure the joint as the operation requires. Moreover, the
operator would be exposed to those dangerous fumes, which, on this
occasion, rush out, and enter the lungs, with such incredible activity
as to threaten instant suffocation.
Having said so much of the elasticity and activity of the fumes of
Spirit of Salt, it is needless to insist upon the necessity of giving
vent to the vessels from time to time, by opening the little hole of
the ballon: indeed the best way to prevent the loss of a great many
vapours, on this occasion, is to employ adopters, and cover them with
wet canvas, which will cool and condense the vapours they contain.
Public-domain text, read in full here on John Shaqi.
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