Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When the operation is finished, we find a white, saline mass at the
bottom of the retort as in a mould. If this mass be dissolved in water,
and the solution crystallized, it yields a considerable quantity of
Sea-salt that hath not been decomposed, and a Neutral Salt consisting
of the Vitriolic Acid united with the Alkaline basis of that part
which hath been decomposed. This Neutral Salt, which bears the name of
_Glauber_ its inventor, differs from Vitriolated Tartar, or the _Sal de
duobus_, which remains after distilling the Nitrous Acid, especially in
that it is more fusible, more soluble in water, and hath its crystals
differently figured. But as in these two Salts the Acid is the same,
the differences that appear between them must be attributed to the
peculiar nature of the basis of Sea-salt.
Spirit of Salt drawn by the process above described is tainted with a
small mixture of the Vitriolic Acid, carried up by the force of fire
before it had time to combine with the Alkali of the Sea-salt; which
happens likewise to the Nitrous Acid procured in the same manner.
If you desire to have it pure, and absolutely free from the Acid of
Vitriol, it must be distilled a second time from Sea-salt, as the Acid
of Nitre was before directed to be distilled again from fresh Nitre, in
order to purify it from any Vitriolic taint.
Sea-salt, as well as Nitre, may be decomposed by any combination of
the Vitriolic Acid with a metallic or earthy substance: but it is
proper to observe, that if you distil Spirit of Salt by means of Green
Vitriol, the operation will not succeed so well as when Spirit of Nitre
is distilled in the same manner: less Spirit is obtained, and a much
fiercer fire is required.
The cause of this lies in the property which the Acid of Sea-salt
possesses of dissolving Iron, even when deprived of a part of its
Phlogiston by having contracted an union with another Acid; so that it
is no sooner dislodged from its own basis by the Vitriolic Acid, than
it unites with the ferruginous basis of the Vitriol, from which it
cannot be separated but by a most violent fire. This is the consequence
more especially when calcined Vitriol is made use of: for moisture,
as we shall presently see, greatly facilitates the separation of the
Marine Acid from those substances with which it is united.
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