Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When you do not desire a highly dephlegmated and smoking Spirit of
Salt, you may distil with the additament of any earth containing the
Vitriolic Acid; as Clay, for instance, or Bole. To this end one part
of Sea-salt, slightly dried and reduced to a fine powder, must be
accurately mingled with two parts of the earth you intend to employ
likewise pulverized; of this mixture make a stiff paste with a proper
quantity of rain water, and having formed little balls thereof about
the size of a hazel nut, let them dry in the sun; when dry, put them
into a stone or coated glass retort, leaving a third part thereof
empty; set this vessel in a reverberating furnace, covered with its
dome; apply a receiver, which need not be luted on for some time; and
heat the vessels very slowly. At first an insipid water will rise,
which must be thrown away: afterwards the Spirit of Salt will appear
in white clouds. Now lute your vessels, and raise the fire by degrees;
which, towards the end must be pushed to the utmost extremity. The
operation is known to be finished when no drops fall from the nose of
the retort, the receiver cools, and the white vapours that filled it
are seen no more.
The Spirit of Salt obtained by the process here delivered does not
smoke, and contains much more phlegm than that which is distilled by
means of the concentrated Oil of Vitriol; because the earth, though
dried in the sun, still retains a great deal of moisture, which
commixes with the Acid of the Sea-salt. Consequently it is much easier
to collect its vapours; so that this operation is attended with much
less trouble than the other. Nevertheless it is adviseable to proceed
gently; to apply but little heat at first, and to unstop every now and
then the small hole of the receiver: for a quantity of the vapours of
Spirit of Salt, even when weakened by the admixture of water, is very
apt to burst the vessels.
A much greater degree of fire is necessary to raise the Spirit of Salt
by this latter process, than by that in which the pure Vitriolic Acid
is employed: for, as fast as the Spirit of Salt is dislodged from its
own basis, by the Vitriolic Acid contained in the earth made use of,
part of it joins that earth, and cannot be separated from it without
the most violent heat.
A Spirit of Salt that shall not smoke may also be obtained by means of
the pure Vitriolic Acid. Spirit of Vitriol, or Oil of Vitriol, lowered
with a good deal of water, will do the business.
Public-domain text, read in full here on John Shaqi.
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