Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Some Chymists direct a little water to be placed in the receiver, when
Spirit of Salt is to be distilled by the intermedium of concentrated
Oil of Vitriol, in order to make the acid vapours condense more
readily. By this means indeed some of the inconveniencies attending
the distillation of smoking Spirit of Salt may be avoided: but, on the
other hand, the acid vapours being absolutely suffocated by the water
as fast as they come over, the Spirit of Salt obtained by this method
will be no less aqueous than that procured by the interposition of
earths: so that here is an expence to no manner of purpose. Therefore,
when a Spirit of Salt is desired that shall not smoke, it is best
to employ an additament of earth; and that so much the rather as
the Marine Acid obtained by this means is purer and freer from any
Vitriolic taint, for the reasons already assigned.
Part of the Acid of Sea-salt may be separated from its Alkaline basis
by the force of fire alone, without the intervention of any other body.
With this view the Salt must be put into the retort without being
dried. At first an insipid water rises; but it gradually becomes acid,
and hath all the properties of Spirit of Salt. When the Salt in the
retort is grown perfectly dry, nothing more can be forced over by any
degree of heat whatever. If you would obtain more Acid from the same
Salt, you must take it out of the retort, where you will find it in a
lump, reduce it to powder, and expose it to the air for some time, that
it may attract the moisture thereof; or else wet it at once with some
rain water, and distil as before. You will again have an insipid water,
and a little Spirit of Salt; which will in like manner cease to rise
when the Salt in the retort becomes dry. This operation may be repeated
as often as shall be thought proper: and perhaps it may be possible to
decompose Sea-salt entirely by means thereof, without the interposition
of any other body. The Spirit of Salt thus obtained is exceeding weak,
in small quantity, and loaded with much water.
This experiment proves, that moisture greatly facilitates the
separation of the Acid of Sea-salt from the matters with which it is
united: and this is the reason that, in distilling Spirit of Salt with
the additament of an earth, the operation requires much less fire
at the beginning, while the earth and salt retain a great deal of
humidity, than towards the end, when they begin to grow dry.
Public-domain text, read in full here on John Shaqi.
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