Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
After the operation there remains in the retort a saline and earthy
mass, which contains, 1. Some entire Sea-salt that has suffered no
decomposition; 2. A Glauber's Salt which is, as we said before, a
Neutral Salt consisting of the Vitriolic Acid united with the Alkaline
basis of the Sea-salt, from which it hath expelled its proper Acid; 3.
Part of the earth used as an intermedium, still retaining a portion of
its original Vitriolic Acid, which happening not to lie near enough to
any particles of Sea-salt, could not exert its power in decomposing
them, and so remains united with its earthy basis; 4. Another part
of the same earth, impregnated with some of the Marine Acid, which
combined therewith upon being expelled from its Alkaline basis by the
Vitriolic Acid, and which the force of fire was unable to separate
from it when the matters were grown perfectly dry. In consequence
of what remains in this _caput mortuum_, if the whole mass be
triturated, moistened with a little water, and distilled a second time,
considerably more Spirit of Salt will be obtained from it: and the same
is to be said of all distillations of this sort.
Spirit of Salt obtained by the means of any other additament than
concentrated Oil of Vitriol is generally very weak: but it may be
dephlegmated and concentrated, if required, much in the same manner as
Oil of Vitriol. For this purpose you must put it into a glass cucurbit,
set it in a _balneum mariæ_, fit thereto a head and a receiver, and
with a moderate degree of heat draw off one third or one half of the
liquor. What comes over into the receiver will be the most aqueous
part, which being the lightest will rise first, impregnated however
with a little acid: in the cucurbit will be left a concentrated Spirit
of Salt, or the most acid part, which being the heaviest will not rise
with the degree of heat that is capable of carrying up the phlegm.
Spirit of Salt thus concentrated, called also _Oil of Salt_, does not
smoke: it is of a yellow colour inclining to green, and an agreeable
smell, not unlike that of saffron.
PROCESS IV.
_To decompose Sea-salt by means of the Nitrous Acid._ Aqua regis.
_Quadrangular Nitre._
Take dried Sea-salt; bruise it to powder; put it into a glass retort,
leaving one half of the vessel empty. Pour upon it a third of its
weight of good Spirit of Nitre. Place your retort in the sand-bath of a
reverberating furnace; put on the dome; lute to the retort a receiver
having a small hole in it, and heat the vessels very slowly. There will
come over into the receiver some vapours, and an acid liquor. Increase
the fire gradually till nothing more rises. Then unlute the vessels,
and pour the liquor out of the receiver into a crystal bottle, stopped
like others containing Acid Spirits.
_OBSERVATIONS._
Public-domain text, read in full here on John Shaqi.
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