Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The Nitrous Acid hath a greater affinity than the Marine Acid with
fixed Alkalis. When therefore Spirit of Nitre and Sea-salt are mixed
together, the same consequences, in some measure, will follow, as when
the Vitriolic Acid is mixed with that salt; that is, the Nitrous Acid
will, like the Vitriolic, decompose it, by dislodging its Acid from
its Alkaline basis, and assuming its place. But as the Nitrous Acid is
considerably weaker, and much lighter, than the Vitriolic Acid, a good
deal of it rises along with the Acid of Sea-salt during the operation.
The liquor found in the receiver is therefore a true _Aqua regis_.
If decrepitated Salt, and a right smoking Spirit of Nitre, be employed
in this process, the _Aqua regis_ obtained will be very strong; and,
during the operation, very elastic vapours will rush out and burst the
vessels, if those precautions be not taken which we pointed out as
necessary in distilling the Spirit of Nitre, and the smoking Spirit of
Salt.
The operation being finished, there is left in the retort a saline
mass, containing Sea-salt not decomposed, and a new species of Nitre,
which having for its basis the Alkali of Sea-salt, that is, as we have
several times observed, an Alkali of a peculiar nature, differs from
the common Nitre, 1. In the figure of its crystals; which are solids of
four sides, formed like lozenges: 2. In that it crystallizes with more
difficulty, retains more water in its crystals, attracts the moisture
of the air, and dissolves in water with the same circumstances as
Sea-salt.
CHAP. IV.
_Of_ BORAX.
PROCESS.
_To decompose Borax by the means of Acids, and to separate from it the
Sedative Salt by sublimation and by crystallization._
Reduce to a fine powder the Borax from which you intend to extract
the Sedative Salt. Put this powder into a wide-necked glass retort.
Pour upon it an eighth part of its weight of common water, to moisten
the powder; and then add concentrated Oil of Vitriol to the weight of
somewhat more than a fourth part of the weight of Borax. Set the retort
in a reverberatory, make a moderate fire at first, and augment it
gradually till the retort become red-hot.
Public-domain text, read in full here on John Shaqi.
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