Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Antimony is a compound, consisting of a semi-metallic part united with
about a fourth part of its weight of common Sulphur. It appears, in the
ninth column of the Table of Affinities, that all the metals, Mercury
and Gold excepted, have a greater affinity than the reguline part of
Antimony with Sulphur. If therefore Gold, adulterated with a mixture
of Copper, Silver, or any other metal, be melted with Antimony, those
metals will unite with the Sulphur of the Antimony, and separate it
from the reguline part, which being thus set free will combine and be
blended with the Gold. These two metallic substances, forming a mass
far heavier than the other metals mixed with the sulphur, fall together
to the bottom of the crucible in the form of a Regulus, while the
others float over them like a sort of scoria or flag: and thus the Gold
is freed from all alloy but the reguline part of the Antimony.
As all the other metals have a great affinity with Sulphur, and Gold
is the only one that is capable of resisting its action, one would
think Sulphur alone might be sufficient to free it from the metals
combined with it, and that it would therefore be better to employ pure
Sulphur, in this operation, than to make use of Antimony; the reguline
part of which remaining united with the Gold requires another long and
laborious operation to get rid of it.
Indeed, strictly speaking, Sulphur alone would be sufficient to
produce the desired separation: but it is proper to observe, that, as
Sulphur alone is very combustible, most of it would be consumed in
the operation before it could have an opportunity to unite with the
metallic substances; whereas, when it is combined with the Regulus
of Antimony, it is thereby enabled to bear the action of the fire
much longer without burning, and consequently is much fitter for the
purpose in question. Besides, if we were to make use of pure Sulphur,
a great part of the Gold, which is kept in perfect fusion, and its
precipitation facilitated, by the Regulus of Antimony, would remain
confounded with the Sulphureous scoria.
Nevertheless, seeing the metals with which Gold is alloyed cannot
be separated from it by Antimony, but that a quantity of Regulus
proportioned to the quantity of the metals so separated will unite
with the Gold, and that the more Regulus combines with the Gold, the
more tedious, chargeable, and laborious will the operation prove, this
consideration ought to have some influence in directing our process.
Therefore, if the Gold be very impure, and worse than sixteen carats,
we must not mix it with crude Antimony alone, but add two drams of
pure Sulphur for every carat the Gold wants of sixteen, and lessen the
quantity of Antimony in proportion to that of the real Gold.
It is necessary to keep the crucible close covered, after mixing the
Antimony with the Gold, to prevent any coals from falling into it: for,
if that should happen, the melted mass would puff up considerably, and
might perhaps run over.
Public-domain text, read in full here on John Shaqi.
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