Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The inside of the cone, into which you pour the melted metallic mass,
must be greased with tallow, to prevent its sticking thereto, and that
it may come easily out. Striking the floor, on which the cone with the
melted metal stands, helps the precipitation and descent of the Regulus
of Gold and Antimony to the bottom of the cone.
Less fire is requisite to melt this compound Regulus, in order to add
fresh Antimony, than was necessary before the Gold was mixed with the
reguline part of the Antimony; because this metallic substance, being
much more fusible than Gold, promotes its melting. The Antimony is
mixed with the Gold by repeated projections, that the separation of
the metals may be accomplished with the greater ease and accuracy. Yet
the operation might be successfully performed, by putting in all the
Antimony at once, and with one melting only.
The metalline mass found at the bottom of the cone after all these
operations, is a mixture of Gold with the reguline part of the
Antimony. All the rest of the process consists only in separating this
reguline part from the Gold. As Gold is the most fixed of all metals,
and as the Regulus of Antimony cannot bear the violence of fire without
flying off in vapours, nothing more is necessary for this purpose but
to expose the compound, as directed in the process, to a heat strong
enough and long enough continued, to dissipate all the Regulus of
Antimony. This semi-metal exhales in the form of a very thick white
smoke. It is proper to blow gently into the crucible during the whole
operation; because the immediate contact of the fresh air incessantly
thrown in promotes and considerably increases the evaporation: and this
is a general rule applicable to all evaporations.
The fire must be gradually raised as the Regulus of Antimony is
dissipated, and the operation draws towards an end; because the mixed
mass of Regulus of Antimony and Gold becomes so much the less fusible
as the proportion of the Regulus is lessened. Though the Regulus of
Antimony be separated from the Gold in this operation, because the
latter is of such a fixed nature that it cannot be volatilized by the
degree of fire which dissipates the Regulus; yet, as the Regulus is
very volatile, it will undoubtedly carry up some of the Gold along with
it, especially if you hurry on the evaporation too fast, by applying
too great a degree of fire, by blowing too briskly into the crucible,
and still more if you evaporate your mixture in a broad flat vessel
instead of a crucible. All these things must therefore be avoided, if
you would lose no more Gold than you needs must.
Public-domain text, read in full here on John Shaqi.
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