Elements of the Theory and Practice of Chymistry, 5th ed. — John Shaqi
Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
If we inquire what is become of its propensity to unite with water, we
shall find that the earth, which of itself is not soluble in water,
hath, by its union with the Acid, acquired a facility of dissolving
therein; so that our _Sal Salsum_ is soluble in water. But, on the
other hand, the Acid hath, by its union with the earth, lost part of
the affinity it had with water; so that if a _Sal Salsum_ be dried,
and freed of all superfluous humidity, it will remain, in that dry
solid form, instead of attracting the moisture of the air, and running
_per deliquium_, as the Acid would do if it were pure and unmixed
with earth. However, this general rule admits of some exceptions; and
we shall have occasion in another place to take notice of certain
combinations of Acids with earths, which still continue to attract the
moisture of the air, though not so strongly as a pure Acid.
ACIDS have likewise a great affinity with the Phlogiston. When we come
to treat of each Acid in particular, we shall examine the combinations
of each with the Phlogiston: they differ so widely from one another,
and many of them are so little known, that we cannot at present give
any general idea of them.
SECTION II.
_Of_ ALKALIS.
Alkalis are Saline combinations, in which there is a greater proportion
of earth than in Acids. The principal arguments that may be adduced
to prove this fact are these: First; if they be treated in the manner
proposed above for analyzing Saline Substances, we obtain from them
a much greater quantity of earth than we do from Acids. Secondly; by
combining certain Acids with certain earths we can produce Alkalis; or
at least such saline compounds as greatly resemble them. Our third and
last argument is drawn from the properties of those Alkalis which, when
pure and unadulterated with any other principle, have less affinity
with water than Acids have, and are also more fixed, resisting the
utmost force of fire. On this account it is that they have obtained the
title of _Fixed_, as well as to distinguish them from another species
of Alkali, to be considered hereafter, which is impure and volatile.
Though fixed Alkalis, when dry, sustain the utmost violence of fire
without flying off in vapours, it is remarkable that, being boiled with
water in an open vessel, considerable quantities of them rise with the
steam: an effect which must be attributed to the great affinity between
these two substances, by means whereof water communicates some part of
its volatility to the fixed salt.
Alkalis freed of their superfluous humidity by calcination attract the
moisture of the air, but not so strongly as Acids: so that it is easier
to procure and preserve them in a solid form.
They flow in the fire, and are then capable of uniting with vitrifiable
earths, and of forming therewith true glass, which, however, will
partake of their properties, if they be used in sufficient quantity.
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