Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
As they melt more readily than vitrifiable earth, they facilitate its
fusion; so that a weaker fire will reduce it to glass, when a fixed
Alkali is joined with it, than will melt it without that addition.
Alkalis are known by their taste, which is acrid and fiery; and by the
properties they possess of turning vegetable blues and violet colours
green; particularly syrop of violets.
Their affinity with acids is greater than that of absorbent earths; and
hence it comes to pass, that if an Alkali be presented to a combination
of an Acid with an absorbent earth, the earth will be separated from
the Acid by the Alkali, and a new union between the Acid and the Alkali
will take place. This is both an instance and a proof of our fifth
proposition concerning Affinities.
If a pure Alkali be presented to a pure Acid, they rush together with
violence, and produce the same phenomena as were observed in the
union of an absorbent earth with an Acid; but in a greater and more
remarkable degree.
Fixed Alkalis may in general be divided into two sorts: one of these
hath all the above-recited properties; but the other possesses some
that are peculiar to itself. We shall consider this latter sort more
particularly under the head of Sea-Salt.
SECTION III.
_Of_ NEUTRAL SALTS.
The Acid and the Alkali thus uniting mutually rob each other of their
characteristic properties; so that the compound resulting from their
union produces no change in the blue colours of vegetables, and
has a taste which is neither sour nor acrid, but saltish. A saline
combination of this kind is for that reason named _Sal Salsum_, _Sal
Medium_, of a _Neutral Salt_. Such combinations are also called by the
plain general name of _Salts_.
It must be observed that, in order to make these Salts perfectly
Neutral, it is necessary that neither of the two saline principles
of which they are compounded be predominant over the other; for in
that case they will have the properties of the prevailing principle.
The reason is this: neither of these saline substances can unite with
the other but in a limited proportion, beyond which there can be no
further coalition between them. The action by which this perfect union
is accomplished is termed _Saturation_; and the instant when such
proportions of the two saline substances are mixed together, that the
one is incorporated with as much of the other as it can possibly take
up, is called the _Point of Saturation_. All this is equally applicable
to the combination of an Acid with an absorbent earth.
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