Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The portion of Phlogiston retained by the Acid of Sulphur is much more
considerable when that mineral is burnt gradually and slowly: in that
case the vapours which rise from it have such a penetrating odour,
that they instantaneously suffocate any person who draws in a certain
quantity of them with his breath. These vapours constitute what is
called the _Volatile Spirit of Sulphur_. There is reason to think this
portion of Phlogiston which the Acid retains is combined therewith in a
manner different from that in which these two are united in the Sulphur
itself; for, as has just been observed, nothing but actual burning is
capable of separating the Vitriolic Acid and the Phlogiston, which by
their union form Sulphur; whereas in the Volatile Spirit of Sulphur
they separate spontaneously when exposed to the open air; that is, the
Phlogiston flies off and leaves the Acid, which then becomes in every
respect similar to the Vitriolic Acid.
That the Volatile Spirit of Sulphur is a compound, as we have asserted
it to be, appears evidently from hence, that whenever the Vitriolic
Acid touches any substance containing the Phlogiston, provided that
Phlogiston be disengaged or opened to a certain degree, a Volatile
Spirit of Sulphur is infallibly and immediately generated. This Spirit
hath all the properties of Acids, but considerably weakened, and of
course less perceptible. It unites with absorbent earths or fixed
Alkalis; and with them forms Neutral Salts; but when combined therewith
it may be separated from them by the Vitriolic Acid, and indeed by
any of the mineral Acids, because its affinities are weaker. Sulphur
hath the property of uniting with absorbent earths, but not near so
intimately as with fixed Alkalis.
If equal parts of Sulphur and an Alkali be melted together, they
incorporate with each other; and from their conjunction proceeds a
compound of a most unpleasant smell, much like that of rotten eggs,
and of a red colour nearly resembling that of an animal liver, which
has occasioned it to bear the name of _Hepar Sulphuris_, or _Liver of
Sulphur_.
In this composition the fixed Alkali communicates to the Sulphur the
property of dissolving in water: and hence it comes that Liver of
Sulphur may be made as well when the Alkali is dissolved by water into
a fluid, as when it is fused by the action of fire.
Sulphur has less affinity than any Acid with the fixed Alkalis: and
therefore Liver of Sulphur may be decompounded by any Acid whatever;
which will unite with the fixed Alkali, form therewith a Neutral Salt,
and separate the Sulphur.
If Liver of Sulphur be dissolved in water, and an Acid poured thereon,
the liquor, which was transparent before, instantly turns to an opaque
white; because the Sulphur, being forced to quit its union with the
Alkali, loses at the same time the property of dissolving in water, and
appears again in its own opaque form. The liquor thus made white by the
Sulphur is called _Milk of Sulphur_.
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