Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The Vitriolic Acid combined with certain earths forms a kind of
Neutral Salt called _Selenites_, which crystallizes in different forms
according to the nature of its earth. There are numberless springs
of water infected with dissolved Selenites; but when this Salt is
once crystallized, it is exceeding difficult to dissolve it in water
a second time. For that purpose a very great quantity of water is
necessary, and moreover it must boil; for as it cools most of the
dissolved Selenites takes a solid form, and falls in a powder to the
bottom of the vessel.
If an Alkali be presented to the Selenites, or to Alum, these
Salts, according to the principles we have laid down, will be
thereby decomposed; that is, the Acid will quit the earths, and join
the Alkali, with which it hath a greater affinity. And from this
conjunction of the Vitriolic Acid with a fixed Alkali there results
another sort of Neutral Salt, which is called _Arcanum duplicatum_,
_Sal de duobus_, and _Vitriolated Tartar_, because one of the fixed
Alkalis most in use is called Salt of Tartar.
Vitriolated Tartar is almost as hard to dissolve in water as the
Selenites. It shoots into eight-sided crystals, having the apices of
the pyramids pretty obtuse. Its taste is saltish, inclining to bitter;
and it decrepitates on burning coals. It requires a very great degree
of fire to make it flow.
The Vitriolic Acid is capable of uniting with the Phlogiston, or rather
it has a greater affinity with it than with any other body: whence
it follows, that all compounds, of which it makes a part, may be
decomposed by means of the Phlogiston.
From the conjunction of the Vitriolic Acid with the Phlogiston arises
a compound called _Mineral Sulphur_, because it is found perfectly
formed in the bowels of the earth. It is also called _Sulphur vivum_,
or simply _Sulphur_.
Sulphur is absolutely insoluble in water, and incapable of contracting
any sort of union with it. It melts with a very moderate degree of
heat, and sublimes in fine light downy tufts called _Flowers of
Sulphur_. By being thus sublimed, it suffers no decomposition, let
the operation be repeated ever so often; so that Sublimed Sulphur, or
Flower of Sulphur, hath exactly the same properties as Sulphur that has
never been sublimed.
If Sulphur be exposed to a brisk heat in the open air, it takes fire,
burns, and is wholly consumed. This deflagration of Sulphur is the
only means we have of decomposing it, in order to obtain its Acid in
purity. The Phlogiston is destroyed by the flame, and the Acid exhales
in vapours: these vapours collected have all the properties of the
Vitriolic Acid, and differ from it only as they still retain some
portion of the Phlogiston; which, however, soon quits them of its own
accord, if the free access of the common air be not precluded.
Public-domain text, read in full here on John Shaqi.
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